THE SYNTHESIS AND STRUCTURE OF THE FIRST REPRESENTATIVES OF OLIGOARYLENEPHOSPHOCYCLANES

作者: Yu. I. Blokhin , D. V. Gusev , V. K. Belsky , A. I. Stash , E. I. Nifantyev

DOI: 10.1080/10426509508042552

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摘要: Abstract Based on phenylphosphonous acid tetraethyldiamide and 2,2-di(p-oxyphenyl)propane diarylenecyclo-phenylphosphonite is synthesized. Its oxidation sulfurization investigated. It shown that these reactions are stereospecific lead to cis-isomers. The compounds obtained the first representatives of oligoarylenephosphocyclanes. structure confirmed by an X-ray analysis.

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