Decarboxylative radical addition of N -Boc-amino acids to acrylonitrile via photoinduced electron transfer using 1,4-dicyanonaphthalene
作者： Yasuharu Yoshimi , Shota Hayashi , Keisuke Nishikawa , Yoshiki Okita , Kousuke Maeda
DOI: 10.1007/S11164-012-0657-Z
关键词:
摘要: Decarboxylative radical addition of N-(t-butoxycarbonyl)amino acids to acrylonitrile was achieved by excitation 1,4-dicyanonaphthalene. The photochemical decarboxylation highly dependent on the dicyanoarenes used as electron acceptors and a base. photoreaction proceeded smoothly yield decarboxylative adduct even in presence only catalytic amount
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