Unexpected fluorescence properties in an axially σ-bonded ferrocenyl-containing porphyrin

作者: Pavlo V. Solntsev , Jared R. Sabin , Samantha J. Dammer , Nikolay N. Gerasimchuk , Victor N. Nemykin

DOI: 10.1039/C0CC02171G

关键词:

摘要: Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(IV) complex axially σ-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- spectroelectrochemical methods as well DFT calculations X-ray crystallography.

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