Reversible oxygen-binding and facilitated oxygen transport in membranes of polyvinylimidazole complexed with cobalt-phthalocyanine

作者: Nalinakumari Preethi , Hiromi Shinohara , Hiroyuki Nishide

DOI: 10.1016/J.REACTFUNCTPOLYM.2005.11.013

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摘要: Abstract A membrane with an oxygen-binding capability and nanometer thickness was prepared by complexing cobalt-phthalocyanine as oxygen carrier the copolymer of vinylimidazole octyl methacrylate. The complex showed reversible in solution state at low temperature. permeability coefficient ( P O 2 ) through this much higher than that nitrogen N / > 20 increased lower upstream pressure. facilitation transport augmented increasing concentration carrier, fixed membrane.

参考文章(15)
Eishun Tsuchida, Hiroyuki Nishide, Polymer-metal complexes and their catalytic activity Advances in Polymer Science. pp. 1- 87 ,(1977) , 10.1007/3-540-08124-0_1
Jongok Won, Yong Soo Kang, Hiroyuki Nishide, Binding of Small Molecules Wiley‐VCH Verlag GmbH & Co. KGaA. pp. 361- 403 ,(2007) , 10.1002/9783527610778.CH9
Hiroyuki Nishide, Yukihiro Tsukahara, Eishun Tsuchida, Highly selective oxygen permeation through a poly(vinylidene dichloride)-cobalt porphyrin membrane: Hopping transport of oxygen via the fixed cobalt porphyrin carrier Journal of Physical Chemistry B. ,vol. 102, pp. 8766- 8770 ,(1998) , 10.1021/JP9816317
Hiroyuki Nishide, Takayuki Suzuki, Ryuji Nakagawa, Eishun Tsuchida, ENHANCED OXYGEN DIFFUSION THROUGH A POROUS MEMBRANE CHEMICALLY MODIFIED WITH COBALT PORPHYRIN ON ITS PORE SURFACE Journal of the American Chemical Society. ,vol. 116, pp. 4503- 4504 ,(1994) , 10.1021/JA00089A060
Y. Okamoto, Macromolecules-Metal Complexes Chemistry International -- Newsmagazine for IUPAC. ,vol. 24, pp. 29- 29 ,(2002) , 10.1515/CI.2002.24.4.29B
Hiroyuki Nishide, Hiroyoshi Kawakami, Takayuki Suzuki, Yasutaka Azechi, Eishun Tsuchida, Enhanced stability and facilitation in oxygen transport through cobalt porphyrin polymer membranes Macromolecules. ,vol. 23, pp. 3714- 3716 ,(1990) , 10.1021/MA00217A031
Hiromi Shinohara, Takayuki Arai, Hiroyuki Nishide, Oxygen-binding to simple cobaltporphyrins combined with polyvinylmidazole Macromolecular Symposia. ,vol. 186, pp. 135- 139 ,(2002) , 10.1002/1521-3900(200208)186:1<135::AID-MASY135>3.0.CO;2-R
Neil B. McKeown, Phthalocyanine-containing polymers Journal of Materials Chemistry. ,vol. 10, pp. 1979- 1995 ,(2000) , 10.1039/B000793P
Hiromi Shinohara, Hirokazu Shibata, Dieter Wöhrle, Hiroyuki Nishide, Reversible oxygen binding to the polymeric cobalt tetraazaporphyrin complex and oxygen-facilitated transport through its membrane Macromolecular Rapid Communications. ,vol. 26, pp. 467- 470 ,(2005) , 10.1002/MARC.200400591