Characterization of hydrogenolysis products from acidic extracts of low rank coal

作者: Kiyoshi Mashimo , Fumiki Hatanaka , Kiyoshi Kawada , Takaki Miyachi , Tohru Wainai

DOI: 10.1016/0016-2361(90)90243-J

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摘要: Abstract An appreciable amount of acidic substances was extracted from a Japanese lignite using concentrated sodium hydroxide. Long-chain alkanes were found in their hydrogenated products. Their structure and reactivity for the hydrogenolysis suggested that precursors n-alkanes long-chain alkyl groups bound directly through ketones to aromatic rings, presence which confirmed extracts. In contrast, fatty acids could be excluded as source n-alkanes. Thus, coal liquid is elucidated.

参考文章(7)
Kozo Kiya, Kiyoshi Mashimo, Tohru Wainai, Identification of straight-chain fatty acids associated with metallic cations in coals Fuel. ,vol. 66, pp. 1447- 1449 ,(1987) , 10.1016/0016-2361(87)90195-5
Kiyoshi Mashimo, Kozo Kiya, Shinichi Sato, Hideki Tsuchiya, Tohru Wainai, Hydrogenolysis products of pyridine extract of a Japanese lignite Fuel. ,vol. 63, pp. 1417- 1421 ,(1984) , 10.1016/0016-2361(84)90349-1
P NELSON, Chemically-bound n-alkyl groups in coal Fuel. ,vol. 66, pp. 1264- 1268 ,(1987) , 10.1016/0016-2361(87)90065-2
Colin E. Snape, William R. Ladner, Keith D. Bartle, Fate of aliphatic groups in low-rank coals during extraction and pyrolysis processes☆ Fuel. ,vol. 64, pp. 1394- 1400 ,(1985) , 10.1016/0016-2361(85)90341-2
Kozo KIYA, Kiyoshi MASHIMO, Tohru WAINAI, Study on long chain alkyl groups in coals. Bunseki Kagaku. ,vol. 34, pp. 233- 238 ,(1985) , 10.2116/BUNSEKIKAGAKU.34.5_233
Kozo KIYA, Kiyoshi MASHIMO, Tohru WAINAI, Original forms of straight-chain fatty acids in low rank coals. Journal of the Fuel Society of Japan. ,vol. 65, pp. 394- 399 ,(1986) , 10.3775/JIE.65.394