The effect of defect structure due to doping and irradiation on the thermal decomposition of potassium chlorate
作者： W. K. Rudloff , E. S. Freeman
DOI: 10.1007/BF01910222
关键词:
摘要: The thermal decomposition of potassium chlorate was investigated as a function doping and there seems to be correlation between the polarizing nature dopant cation degradation temperature chlorate. In particular, transition metal cations influence strongly decomposition. Irradiation mechanical shock defects also process. A possible mechanism in terms semi-conductive properties defective chlorates is discussed.
springer.com
sci-hub.se 参考文章(12)
Heinrich Remy, Lehrbuch der anorganischen Chemie Akademische Verlagsgesellschaft. ,(1959)
Robert C. Ph.D. Weast, Handbook of Chemistry and Physics ,(1970)
W. K. Rudloff, E. S. Freeman, The catalytic effects of metal oxides on thermal decomposition reactions, III Journal of Thermal Analysis and Calorimetry. ,vol. 18, pp. 359- 369 ,(1980) , 10.1007/BF02055821
Winfried K. Rudloff, Eli S. Freeman, Catalytic effect of metal oxides on thermal-decomposition reactions. I. The mechanism of the molten-phase thermal decomposition of potassium chlorate in mixtures with potassium chloride and potassium perchlorate The Journal of Physical Chemistry. ,vol. 73, pp. 1209- 1215 ,(1969) , 10.1021/J100725A006
Winfried K. Rudloff, Eli S. Freeman, Catalytic effect of metal oxides on thermal decomposition reactions. II. Catalytic effect of metal oxides on the thermal decomposition of potassium chlorate and potassium perchlorate as detected by thermal analysis methods The Journal of Physical Chemistry. ,vol. 74, pp. 3317- 3324 ,(1970) , 10.1021/J100712A002
Meyer M. Markowitz, Daniel A. Boryta, Harvey Stewart, The Differential Thermal Analysis of Perchlorates. VI. Transient Perchlorate Formation during the Pyrolysis of the Alkali Metal Chlorates1 The Journal of Physical Chemistry. ,vol. 68, pp. 2282- 2289 ,(1964) , 10.1021/J100790A043
Raymond M. Fuoss, Ival O. Salyer, Harry S. Wilson, Evaluation of rate constants from thermogravimetric data Journal of Polymer Science Part A. ,vol. 2, pp. 3147- 3151 ,(1964) , 10.1002/POL.1964.100020713
Meyer M. Markowitz, Daniel A. Boryta, The Differential Thermal Analysis of Perchlorates. VII. Catalytic Decompositions of the Alkali Metal Perchlorates by Manganese Dioxide The Journal of Physical Chemistry. ,vol. 69, pp. 1114- 1123 ,(1965) , 10.1021/J100888A005
E. L. Wagner, Bond Character in XYM‐Type Molecules: Chlorine—Oxygen Compounds The Journal of Chemical Physics. ,vol. 37, pp. 751- 759 ,(1962) , 10.1063/1.1733157
F. Solymosi, The Thermal Stability and Some Physical Properties of Silver Chlorite, Chlorate and Perchlorate* Zeitschrift für Physikalische Chemie. ,vol. 57, pp. 1- 18 ,(1968) , 10.1524/ZPCH.1968.57.1_2.001