Elements of the Thermodynamic Theory of Electrified Interfaces

作者: Gyözö G. Láng , Cesar A. Barbero

DOI: 10.1007/978-3-642-27651-4_2

关键词:

摘要: In Chap. 2, several aspects of the thermodynamic theory and their physical interpretation are discussed, a simple concise treatment electrified interfaces within framework classical thermodynamics is presented. Basic concepts such as “surface,” “interface,” “interphase,” “interfacial or interface region,” “dividing surface,” “adsorption” reviewed; Gibbs Guggenheim models in interfacial discussed. The derivation electrocapillary equation, Lippmann adsorption equation for an ideally polarizable electrode An example application provided. has been derived electrodes case which there no complete equilibrium between bulk solid interface.

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