Partial charge transfer during anion adsorption. Methodological aspects

摘要: Abstract Some problems of applying the Lippmann equation to ionic adsorption on solid electrodes are considered. The possibility using a nonthermodynamic approach certain thermodynamic (particularly, role elastic and plastic deformations electrode surfaces in processes, polarity surface bonds during anion adsorption, others) is discussed. extremely thin layer affected electrically mechanically by adsorbate considered be free dislocations because volume discrepancy. nearest structure-mechanical analogs such layers whiskers’-type crystals whose side could have point-, one- two-dimensional defects, but not dislocations. Like whiskers, metal ought possess an ultimate strength close theoretical one (0.2E) purely deformation up 0.04. (affected only) should as absolutely body, impossible. It means that simple other equations containing terms cannot used thermodynamics surface. Coefficients partial charge transfer electrosorption valence anions, well electron tunneling formation contact electric resistance (CER) signal relation between anions reconstruction monocrystalline analyzed. beginning substantial proposed trigger process. nature solvent molecules shown play decisive adsorption. results compared available literature data.