The adiabatic limit and the semiclassical limit

作者: M V Berry

DOI: 10.1088/0305-4470/17/6/018

关键词:

摘要: The evolution mod Psi (t)) of a system with slowly-varying Hamiltonian H( Omega t) depends not only on the slowness parameter but also Planck's constant h(cross). For systems two (or more) classically separated phase-space regions which are quantally connected by tunnelling, curves instantaneous energy levels display hyperbolic near-degeneracies rather than crossings. In such cases limits to 0 (h(cross) fixed and small) h(cross) ( lead opposite behaviour (t)). As an illustration, uniform semiclassical adiabatic small, /h(cross) arbitrary) is calculated exactly for double-well potential one well gets shallower as other deeper.

参考文章(15)
M. V. Berry, Aspects of Degeneracy ASIB. ,vol. 120, pp. 123- 140 ,(1985) , 10.1007/978-1-4613-2443-0_8
M. V. Berry, Regular and irregular motion In: Topics in nonlinear dynamics: A tribute to Sir Edward Bullard; Proceedings of the Workshop. ,vol. 46, pp. 16- 120 ,(2008) , 10.1063/1.31417
Jenn‐Tai Hwang, Philip Pechukas, The adiabatic theorem in the complex plane and the semiclassical calculation of nonadiabatic transition amplitudes The Journal of Chemical Physics. ,vol. 67, pp. 4640- 4653 ,(1977) , 10.1063/1.434630
A. G. Fox, Wave Coupling by Warped Normal Modes Bell System Technical Journal. ,vol. 34, pp. 823- 852 ,(1955) , 10.1002/J.1538-7305.1955.TB03778.X
Non-Adiabatic Crossing of Energy Levels Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 137, pp. 696- 702 ,(1932) , 10.1098/RSPA.1932.0165
M V Berry, K E Mount, Semiclassical approximations in wave mechanics Reports on Progress in Physics. ,vol. 35, pp. 315- 397 ,(1972) , 10.1088/0034-4885/35/1/306
N. Fröman, P.O. Fröman, U. Myhrman, R. Paulsson, On the quantal treatment of the double-well potential problem by means of certain phase-integral approximations Annals of Physics. ,vol. 74, pp. 314- 323 ,(1972) , 10.1016/0003-4916(72)90143-1
Ramakrishna Ramaswamy, R. A. Marcus, On the onset of chaotic motion in deterministic systems Journal of Chemical Physics. ,vol. 74, pp. 1385- 1393 ,(1981) , 10.1063/1.441202
Ramakrishna Ramaswamy, R. A. Marcus, Perturbative examination of avoided crossings Journal of Chemical Physics. ,vol. 74, pp. 1379- 1384 ,(1981) , 10.1063/1.441201
J. S. Cook, Tapered Velocity Couplers Bell System Technical Journal. ,vol. 34, pp. 807- 822 ,(1955) , 10.1002/J.1538-7305.1955.TB03777.X