Synthesis and Morphology of New Discogenic Phthalocyanine Derivatives
作者： Iwhan Cho , Youngsoo Lim
DOI: 10.1080/00268948808078718
关键词:
摘要: Abstract New discogens based on the octasubstituted phthalocyanines (Pc) were synthesized: 2,3,9,10,16,17,23,24-octakis[dodecylthio-1-methyl]-phthalocyanine (1a), 2,3,9,10,16,17,23,24-octakis[4-(dodecylthio)-2-oxa-butyl]-phthalocyanine (1b), 2,3,9,10,16,17,23,24-octakis[dodecyloxy]-phthalocyanine (1c), phthalocyanine 2,3,9,10,16,17,23,24-octa-n-dodecanoate (1d), S-(+)-2,3,9,10,16,17,23,24-octakis[4-(dodecyloxy)-2-oxa-pentyl]-phthalocyanine (1e), as well their corresponding copper complexes (CuPc) 2a, 2b, 2c and 2e. They characterized by microanalysis, IR, 1H 13C NMR spectroscopies, mesomorphic behaviors examined with DSC optical microscopic methods. The products exhibited following textures transition temperature ranges: focal conic (1a, 95-267°; 108-304°), linear default (1b, 52-247°; 70-255°; 1c, 75-269°; 2c, 78-310°), fan-shaped (1d, 58-303°; 2e, 29-191°). Chiral discogenic PcH2 1e, however, showed a cholestericlike texture (23-151°C) in which ...
sci-hub.se 参考文章(19)
Georg Pawlowski, Michael Hanack, A CONVENIENT SYNTHESIS OF OCTASUBSTITUTED PHTHALOCYANINES Synthesis. ,vol. 1980, pp. 287- 289 ,(1980) , 10.1055/S-1980-28993
Christian Piechocki, Jacques Simon, Antoine Skoulios, Daniel Guillon, Patrick Weber, Annelides. 7. Discotic mesophases obtained from substituted metallophthalocyanines. Toward liquid crystalline one-dimensional conductors Journal of the American Chemical Society. ,vol. 104, pp. 5245- 5247 ,(1982) , 10.1021/JA00383A050
Edward A. Cuellar, Tobin J. Marks, Synthesis and Characterization of Metallo and Metal-Free Octaalkylphthalocyanines and Uranyl Decaalkylsuperphthalocyanines Inorganic Chemistry. ,vol. 20, pp. 3766- 3770 ,(1981) , 10.1021/IC50225A039
C. Destrade, M. C. Mondon-Bernaud, Nguyen Huu Tinh, Mesomorphic Polymorphism in Some Disc-Like Compounds Molecular Crystals and Liquid Crystals. ,vol. 49, pp. 169- 174 ,(1979) , 10.1080/00268947908070455
Dieter Wöhrle, Gunter Meyer, Bernd Wahl, Polymere phthalocyanine und ihre vorstufen, 1. Reaktive oktafunktionelle phthalocyanine aus 1,2,4,5-tetracyanbenzol Die Makromolekulare Chemie. ,vol. 181, pp. 2127- 2135 ,(1980) , 10.1002/MACP.1980.021811010
Paul J. Brach, Steven J. Grammatica, Oliver A. Ossanna, Lester Weinberger, Improved synthesis of metal-free phthalocyanines Journal of Heterocyclic Chemistry. ,vol. 7, pp. 1403- 1405 ,(1970) , 10.1002/JHET.5570070630
Nguyen Huu Tinh, C. Destrade, H. Gasparoux, Nematic disc-like liquid crystals Physics Letters A. ,vol. 72, pp. 251- 254 ,(1979) , 10.1016/0375-9601(79)90019-7
D. Coates, G.W. Gray, A correlation of optical features of amorphous liquid-cholesteric liquid crystal transitions Physics Letters A. ,vol. 51, pp. 335- 336 ,(1975) , 10.1016/0375-9601(75)90634-9
D. Guillon, A. Skoulios, C. Piechocki, J. Simon, P. Weber, Discotic Mesophases of the Metal-Free Derivative of Octa (Dodecyloxymethyl) Phthalocyanine Molecular Crystals and Liquid Crystals. ,vol. 100, pp. 275- 284 ,(1983) , 10.1080/00268948308075357
A. M. Levelut, Structure of a disk-like mesophase Journal De Physique Lettres. ,vol. 40, pp. 81- 84 ,(1979) , 10.1051/JPHYSLET:0197900400408100