Characterization of homogeneous ethylene/1‐octene copolymers made with a single‐site catalyst. CRYSTAF analysis and calibration
作者： Benjam�n Monrabal , Javier Blanco , Jes�s Nieto , Jo�o B.P. Soares
DOI: 10.1002/(SICI)1099-0518(19990101)37:1<89::AID-POLA10>3.0.CO;2-#
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摘要: The crystallizability of narrow composition, homogeneous ethylene/1-octene copolymers made with a constrained geometry catalyst, measured by CRYSTAF, follows straight line correlation the amount total comonomer incorporated. potential use these resins as standards to calibrate CRYSTAF and TREF techniques is discussed. Although most analyzed have chemical composition distribution, there seems be relation between broadness distribution molecular weight, predicted Stockmayer's bivariate distribution.
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