Char‐supported Fe–Zn–Cu sorbent prepared by ultrasonic‐assisted impregnation for simultaneous removal of H2S and COS from coke oven gas

作者: Jinxiao Dou , Arash Tahmasebi , Xianchun Li , Fengkui Yin , Jianglong Yu

DOI: 10.1002/EP.12224

关键词:

摘要: Lignite char supported Fe–Zn–Cu sorbents were prepared by ultrasonic-assisted impregnation method for the simultaneous removal of H2S and COS from coke oven gas (COG). Sulfidation experiments carried out in a fixed-bed quartz reactor using simulated COG. The results showed that addition Cu can significantly increase sulfidation reactivity char-supported Fe–Zn sorbents. Char-supported with Fe:Zn:Cu molar ratio 2:1:0.5 could simultaneously remove temperature range 200–400°C. sulfur capacity reached to 17.62 g S per 100 sorbent at 400°C. X-ray diffraction (XRD) analysis suggested into leads formation composite oxides. © 2015 American Institute Chemical Engineers Environ Prog, 35: 352–358, 2016

参考文章(37)
T KO, H CHU, Y LIOU, A study of Zn-Mn based sorbent for the high-temperature removal of H2S from coal-derived gas. Journal of Hazardous Materials. ,vol. 147, pp. 334- 341 ,(2007) , 10.1016/J.JHAZMAT.2007.01.018
G. Kliche, Z. V. Popovic, Far-infrared spectroscopic investigations on CuO Physical Review B. ,vol. 42, pp. 10060- 10066 ,(1990) , 10.1103/PHYSREVB.42.10060
Eiji Sasaoka, Makoto Hatori, Hiroyuki Yoshimura, Caili Su, Md. Azhar Uddin, Role of H2O in Oxidation of Spent High-Temperature Desulfurization Sorbent Fe2O3and CuO in the Presence of O2 Industrial & Engineering Chemistry Research. ,vol. 40, pp. 2512- 2517 ,(2001) , 10.1021/IE000940S
Singfoong Cheah, Yves O. Parent, Whitney S. Jablonski, Todd Vinzant, Jessica L. Olstad, Manganese and ceria sorbents for high temperature sulfur removal from biomass-derived syngas – The impact of steam on capacity and sorption mode Fuel. ,vol. 97, pp. 612- 620 ,(2012) , 10.1016/J.FUEL.2012.03.007
Li-Ping Chang, Zong-You Zhang, Xiu-Rong Ren, Fan Li, Ke-Chang Xie, Study on the Stability of Sorbents Removing H2S from Hot Coal Gas Energy & Fuels. ,vol. 23, pp. 762- 765 ,(2009) , 10.1021/EF8005838
Eiji Sasaoka, Yukimasa Iwamoto, S. Hirano, M. Azhar Uddin, Yusaku Sakata, Soot formation over zinc ferrite high-temperature desulfurization sorbent Energy & Fuels. ,vol. 9, pp. 344- 353 ,(1995) , 10.1021/EF00050A020
Zhihong Zhang, Huijun Liang, Xiaogang Du, Xiaoliang Zuo, H2S removal: Correlation between performance and loading species of Zn-Fe/attapulgite Environmental Progress. ,vol. 33, pp. 378- 384 ,(2014) , 10.1002/EP.11787
Dehai Wang, Jianglong Yu, Liping Chang, Dongmei Wang, Effects of addition of Mo on the sulfidation properties of Fe-based sorbents supported on fly ash during hot coal gas desulfurization Chemical Engineering Journal. ,vol. 166, pp. 362- 367 ,(2011) , 10.1016/J.CEJ.2010.11.008
J. Mi, G. Feng, L. Han, T. Guo, Y. Zhu, J. Wang, Modified Semi-Coke-Supported Cerium Oxide-Doped Zinc Ferrites for the Removal of H2S from Coal Gas Chemical Engineering & Technology. ,vol. 35, pp. 1626- 1631 ,(2012) , 10.1002/CEAT.201100540
Venkata Swamy Nalajala, Vijayanand S. Moholkar, Investigations in the physical mechanism of sonocrystallization. Ultrasonics Sonochemistry. ,vol. 18, pp. 345- 355 ,(2011) , 10.1016/J.ULTSONCH.2010.06.016