Quantitative and sensitive mapping of imidacloprid on plants using multiphoton electron extraction spectroscopy

作者: Anneli Kruve , Valery Bulatov , Israel Schechter

DOI: 10.1016/J.CHEMPHYS.2018.03.031

关键词:

摘要: Abstract Neonicotinoids, including imidacloprid, are extensively used for plant protection against insects. Unfortunately, these effective pesticides one of the reasons decline bee population in recent decades. Ensuring application minimal pesticide quantity and preventing excess requires a fast method monitoring coverage on plants. We present new, based multiphoton electron extraction spectroscopy (MEES), detecting, quantifying mapping imidacloprid Imaging quantitative analyses were demonstrated several surfaces olive mint leaves orange peel. Method provides both low detection limits (down to nanogram level) good trueness. This is can be directly performed with no sample pre-treatment, thus, it candidate field analyses.

参考文章(18)
Stefanie Gerbig, Hubertus E. Brunn, Bernhard Spengler, Sabine Schulz, Spatially resolved investigation of systemic and contact pesticides in plant material by desorption electrospray ionization mass spectrometry imaging (DESI-MSI) Analytical and Bioanalytical Chemistry. ,vol. 407, pp. 7379- 7389 ,(2015) , 10.1007/S00216-015-8900-2
Yuheng Chen, Valery Bulatov, Natalia Vinerot, Israel Schechter, Multiphoton ionization spectroscopy as a diagnostic technique of surfaces under ambient conditions. Analytical Chemistry. ,vol. 82, pp. 3454- 3456 ,(2010) , 10.1021/AC100539X
Nataly Vinerot, Yuheng Chen, Valery Bulatov, Vladimir V. Gridin, Victoria Fun-Young, Israel Schechter, Spectral characterization of surfaces using laser multi-photon ionization Optical Materials. ,vol. 34, pp. 329- 335 ,(2011) , 10.1016/J.OPTMAT.2011.05.016
Ravid Ben-Zur, Harald Hake, Salah Hassoon, Valery Bulatov, Israel Schechter, Optical analytical methods for detection of pesticides Reviews in Analytical Chemistry. ,vol. 30, pp. 123- 139 ,(2011) , 10.1515/REVAC.2011.104
Steven Van Timmeren, John C Wise, Christine VanderVoort, Rufus Isaacs, Comparison of foliar and soil formulations of neonicotinoid insecticides for control of potato leafhopper, Empoasca fabae (Homoptera: Cicadellidae), in wine grapes Pest Management Science. ,vol. 67, pp. 560- 567 ,(2011) , 10.1002/PS.2097
Motohiro Tomizawa, John E. Casida, NEONICOTINOID INSECTICIDE TOXICOLOGY: Mechanisms of Selective Action Annual Review of Pharmacology and Toxicology. ,vol. 45, pp. 247- 268 ,(2005) , 10.1146/ANNUREV.PHARMTOX.45.120403.095930
Kuang-Li Lee, Meng-Lin You, Chia-Hsin Tsai, En-Hung Lin, Shu-Yi Hsieh, Ming-Hsun Ho, Ju-Chun Hsu, Pei-Kuen Wei, Nanoplasmonic biochips for rapid label-free detection of imidacloprid pesticides with a smartphone. Biosensors and Bioelectronics. ,vol. 75, pp. 88- 95 ,(2016) , 10.1016/J.BIOS.2015.08.010
Dave Goulson, REVIEW: An overview of the environmental risks posed by neonicotinoid insecticides Journal of Applied Ecology. ,vol. 50, pp. 977- 987 ,(2013) , 10.1111/1365-2664.12111
Anne Fairbrother, John Purdy, Troy Anderson, Richard Fell, Risks of Neonicotinoid Insecticides to Honeybees Environmental Toxicology and Chemistry. ,vol. 33, pp. 719- 731 ,(2014) , 10.1002/ETC.2527
Asko Laaniste, Ivo Leito, Riin Rebane, Rünno Lõhmus, Ants Lõhmus, Fredrik Punga, Anneli Kruve, Determination of neonicotinoids in Estonian honey by liquid chromatography-electrospray mass spectrometry. Journal of Environmental Science and Health Part B-pesticides Food Contaminants and Agricultural Wastes. ,vol. 51, pp. 455- 464 ,(2016) , 10.1080/03601234.2016.1159457