On-surface assembly of low-dimensional Pb-coordinated metal–organic structures

作者: Guoqing Lyu , Ran Zhang , Xin Zhang , Pei Nian Liu , Nian Lin

DOI: 10.1039/C5TC00296F

关键词:

摘要: Novel low-dimensional metal–organic structures incorporating heavy metal Pb atoms as coordination centres are formed on a Au(111) surface by means of on-surface metallo-supramolecular assembly. The molecular building blocks porphyrin derivatives functionalized with pyridyl groups. These linked via unique pyridyl–Pb–pyridyl motif that does not exist in conventional chemistry but emerges the surface. coordinated distinctive morphologies, including one-dimensional single chains, double-chains and ladders, two-dimensional porous networks, owing to specific sites groups blocks.

参考文章(39)
Nian Lin, Sebastian Stepanow, Mario Ruben, Johannes V. Barth, Surface-confined supramolecular coordination chemistry. Topics in Current Chemistry. ,vol. 287, pp. 1- 44 ,(2008) , 10.1007/128_2008_150
En-Cui Yang, Jian Li, Bin Ding, Qing-Qing Liang, Xiu-Guang Wang, Xiao-Jun Zhao, None, An eight-connected 3D lead(II) metal–organic framework with octanuclear lead(II) as a secondary building unit: synthesis, characterization and luminescent property CrystEngComm. ,vol. 10, pp. 158- 161 ,(2008) , 10.1039/B709810C
Tao Lin, Xue Song Shang, Jinne Adisoejoso, Pei Nian Liu, Nian Lin, Steering on-surface polymerization with metal-directed template. Journal of the American Chemical Society. ,vol. 135, pp. 3576- 3582 ,(2013) , 10.1021/JA311890N
Brandon J. Greer, Vladimir K. Michaelis, Michael J. Katz, Daniel B. Leznoff, Georg Schreckenbach, Scott Kroeker, Characterising Lone‐Pair Activity of Lead(II) by 207Pb Solid‐State NMR Spectroscopy: Coordination Polymers of [N(CN)2]− and [Au(CN)2]− with Terpyridine Ancillary Ligands Chemistry: A European Journal. ,vol. 17, pp. 3609- 3618 ,(2011) , 10.1002/CHEM.201002913
Karen J. Nordell, Kristin N. Schultz, Khadine A. Higgins, Mark D. Smith, Hydrothermal synthesis of two new lead-containing coordination polymers: 2∞[PbCl2(4,4′-bipy)] and 2∞[Pb2(NO3)4(H2O)2(4,4′-bipy)2](4,4′-bipy)2 Polyhedron. ,vol. 23, pp. 2161- 2167 ,(2004) , 10.1016/J.POLY.2004.06.012
Liat Shimoni-Livny, Jenny P. Glusker, Charles W. Bock, Lone Pair Functionality in Divalent Lead Compounds Inorganic Chemistry. ,vol. 37, pp. 1853- 1867 ,(1998) , 10.1021/IC970909R
Lei Zhang, Zhao-Ji Li, Qi-Pu Lin, Ye-Yan Qin, Jian Zhang, Pei-Xiu Yin, Jian-Kai Cheng, Yuan-Gen Yao, None, Synthesis, structure, and luminescent properties of hybrid inorganic-organic framework materials formed by lead aromatic carboxylates: inorganic connectivity variation from 0D to 3D. Inorganic Chemistry. ,vol. 48, pp. 6517- 6525 ,(2009) , 10.1021/IC900425R
Steven L. Tait, Alexander Langner, Nian Lin, Sebastian Stepanow, Chandrasekar Rajadurai, Mario Ruben, Klaus Kern, One-Dimensional Self-Assembled Molecular Chains on Cu(100): Interplay between Surface-Assisted Coordination Chemistry and Substrate Commensurability Journal of Physical Chemistry C. ,vol. 111, pp. 10982- 10987 ,(2007) , 10.1021/JP071100V
Tzu-Chun Tseng, Chensheng Lin, Xingqiang Shi, Steven L. Tait, Xiong Liu, Ulrich Starke, Nian Lin, Ruiqin Zhang, Christian Minot, M. A. Van Hove, Jorge I. Cerdá, Klaus Kern, Two-dimensional metal-organic coordination networks of Mn-7,7,8,8-tetracyanoquinodimethane assembled on Cu(100): Structural, electronic, and magnetic properties Physical Review B. ,vol. 80, pp. 155458- ,(2009) , 10.1103/PHYSREVB.80.155458
Z.F Wang, Zheng Liu, Feng Liu, Organic topological insulators in organometallic lattices Nature Communications. ,vol. 4, pp. 1471- ,(2013) , 10.1038/NCOMMS2451