Nanopatterning of alkyl monolayers covalently bound to Si(111) with an atomic force microscope

作者: Masato Ara , Harald Graaf , Hirokazu Tada

DOI: 10.1063/1.1467973

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摘要: Alkyl monolayers covalently bound to silicon were prepared through the reaction between 1-alkene molecules and hydrogen-terminated Si. The surfaces anodized in nanometer scale with a contact-mode atomic force microscope (AFM) by applying positive bias voltage surface respect conducting cantilever under ambient conditions. Following anodization, patterned areas selectively modified chemical etching coating different molecules. alkyl showed high resistance against protected Si from oxidation. AFM lithography of on was found be useful for nanofabrication organic/inorganic interfaces based Si–C covalent bond.

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