Hydroxyl-terminated poly(ethyleneimine) polymer enhanced ultrafiltration for boron removal
作者： Jen Ga Neo , Susilo Japip , Lin Luo , Tai-Shung Chung , Martin Weber
DOI: 10.1016/J.SEPPUR.2019.04.006
关键词:
摘要: Abstract Boron removal is an important separation process which requires excessive operational cost owing to the complex nature of boron in aqueous solutions. Polymer-enhanced ultrafiltration (PEUF) has been widely adopted for due low and high productivity. In this study, novel hydroxyl-terminated poly(ethyleneimine) (HPEI) polymers; namely, HPEI-Diol HPEI-Gluconamide, were designed synthesized as chelating polymers. A polyphenylenesulfone (PPSU) UF membrane was fabricated have a pure water permeance around 82.8 L.m−2.h−1.bar−1 with molecular weight cut off (MWCO) 128 kDa. The rejection coefficient pristine PPSU 6.38% attributed negatively charged surface membrane. Introducing either HPEI or polymer into feed solution increased 45%. Meanwhile, HPEI-Gluconamide found possess highest retention efficiency 94% at pH 4, may be ascribed higher number grafted hydroxyl groups.
cheric.org参考文章(38)
Socrates George, None, Infrared and Raman Characteristic Group Frequencies: Tables and Charts ,(2004)
Fyodor S. Kot, Boron in the Environment Boron Separation Processes. pp. 1- 33 ,(2015) , 10.1016/B978-0-444-63454-2.00001-0
Ceren Oktar Doğanay, H. Önder Özbelge, Niyazi Bıçak, Nihal Aydoğan, Levent Yılmaz, Use of Specifically Tailored Chelating Polymers for Boron Removal from Aqueous Solutions by Polymer Enhanced Ultrafiltration Separation Science and Technology. ,vol. 46, pp. 581- 591 ,(2011) , 10.1080/01496395.2010.530636
JEFFREY L. PARKS, MARC EDWARDS, Boron in the Environment Critical Reviews in Environmental Science and Technology. ,vol. 35, pp. 81- 114 ,(2005) , 10.1080/10643380590900200
Enver Güler, Cüneyt Kaya, Nalan Kabay, Müşerref Arda, Boron removal from seawater: State-of-the-art review Desalination. ,vol. 356, pp. 85- 93 ,(2015) , 10.1016/J.DESAL.2014.10.009
Çerağ Dilek, Hilmi Önder Özbelge, Niyazi Biçak, Levent Yılmaz, Removal of boron from aqueous solutions by continuous polymer-enhanced ultrafiltration with polyvinyl alcohol Separation Science and Technology. ,vol. 37, pp. 1257- 1271 ,(2002) , 10.1081/SS-120002610
Mohamed Mahmoud Nasef, Madana Nallappan, Zaini Ujang, Polymer-based chelating adsorbents for the selective removal of boron from water and wastewater: A review Reactive & Functional Polymers. ,vol. 85, pp. 54- 68 ,(2014) , 10.1016/J.REACTFUNCTPOLYM.2014.10.007
S Singh, K.C Khulbe, T Matsuura, P Ramamurthy, MEMBRANE CHARACTERIZATION BY SOLUTE TRANSPORT AND ATOMIC FORCE MICROSCOPY Journal of Membrane Science. ,vol. 142, pp. 111- 127 ,(1998) , 10.1016/S0376-7388(97)00329-3
Hasan Zerze, H. Onder Ozbelge, Niyazi Bicak, Nihal Aydogan, Levent Yilmaz, Novel boron specific copolymers with quaternary amine segments for efficient boron removal via PEUF Desalination. ,vol. 310, pp. 169- 179 ,(2013) , 10.1016/J.DESAL.2012.07.035
Yu-Ting Wei, Yu-Ming Zheng, J. Paul Chen, Design and fabrication of an innovative and environmental friendly adsorbent for boron removal. Water Research. ,vol. 45, pp. 2297- 2305 ,(2011) , 10.1016/J.WATRES.2011.01.003