Conformation-Dependent Design of Synthetic Functional Copolymers

摘要: A survey is given of theoretical and experimental methods as applied to the design nontrivial sequences in synthetic copolymers aimed at achieving desired functional properties. We consider a recently developed approach, called conformation-dependent sequence design, which based on assumption that copolymer obtained under certain preparation conditions able ‘remember’ features original conformation it was built store corresponding information resulting sequence. The emphasis exhibiting large-scale compositional heterogeneities long-range statistical correlations between monomer units. Several new strategies polymerization processes allow synthesis with broad variation their distributions are discussed.