Interaction of electron acceptors with bases—XIII

作者: R. Foster , P. Hanson

DOI: 10.1016/S0040-4020(01)98265-1

关键词:

摘要: Abstract Visible absorption studies of the system indole-tetracyanoethylene in dichloromethane show that an intermolecular charge-transfer complex is initially formed. This decomposes to yield a second product, presumed be σ-complex, which finally yields 3-tricyanovinylindole.

参考文章(6)
Robert S. Mulliken, MOLECULAR COMPOUNDS AND THEIR SPECTRA. 3. THE INTERACTION OF ELECTRON DONORS AND ACCEPTORS The Journal of Physical Chemistry. ,vol. 56, pp. 801- 822 ,(1952) , 10.1021/J150499A001
G. N. Sausen, V. A. Engelhardt, W. J. Middleton, Cyanocarbon Chemistry. VII.1 Tricyanoethylenes Journal of the American Chemical Society. ,vol. 80, pp. 2815- 2822 ,(1958) , 10.1021/JA01544A057
Robert S. Mulliken, Molecular Compounds and their Spectra. II Journal of the American Chemical Society. ,vol. 74, pp. 811- 824 ,(1952) , 10.1021/JA01123A067
H. A. Benesi, J. H. Hildebrand, A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons Journal of the American Chemical Society. ,vol. 71, pp. 2703- 2707 ,(1949) , 10.1021/JA01176A030