Production of alkyl esters from macaw palm oil by a sequential hydrolysis/esterification process using heterogeneous biocatalysts: optimization by response surface methodology.

作者： Ana Paula P Bressani , Karen CA Garcia , Daniela B Hirata , Adriano A Mendes , None

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摘要: The present study deals with the enzymatic synthesis of alkyl esters emollient properties by a sequential hydrolysis/esterification process (hydroesterification) using unrefined macaw palm oil from pulp seeds (MPPO) as feedstock. Crude extract dormant castor bean was used biocatalyst in production free fatty acids (FFA) hydrolysis MPPO. Esterification purified FFA several alcohols heptane medium catalyzed immobilized Thermomyces lanuginosus lipase (TLL) on poly-hydroxybutyrate (PHB) particles. Under optimal experimental conditions (mass ratio oil:buffer 35 % m/m, reaction temperature °C, concentration 6 and stirring speed 1,000 rpm), complete MPPO reached after 110 min reaction. Maximum ester conversion percentage 92.4 ± 0.4 hexanol acyl acceptor at 750 mM each reactant 15 retained full activity eight successive cycles esterification These results show that proposed is promising strategy for industrial interest oil, an attractive option Brazilian oleochemical industry.

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参考文章(38)

M.E. Borges, L. Díaz, Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review Renewable & Sustainable Energy Reviews. ,vol. 16, pp. 2839- 2849 ,(2012) , 10.1016/J.RSER.2012.01.071

Ganapati D. Yadav, K.Manjula Devi, Immobilized lipase-catalysed esterification and transesterification reactions in non-aqueous media for the synthesis of tetrahydrofurfuryl butyrate: comparison and kinetic modeling Chemical Engineering Science. ,vol. 59, pp. 373- 383 ,(2004) , 10.1016/J.CES.2003.09.034

Diniara Soares, Andrei Ferreira Pinto, Alan Guilherme Gonçalves, David Alexander Mitchell, Nadia Krieger, Biodiesel production from soybean soapstock acid oil by hydrolysis in subcritical water followed by lipase-catalyzed esterification using a fermented solid in a packed-bed reactor Biochemical Engineering Journal. ,vol. 81, pp. 15- 23 ,(2013) , 10.1016/J.BEJ.2013.09.017

Shinji Hama, Ayumi Yoshida, Naoki Tamadani, Hideo Noda, Akihiko Kondo, Enzymatic production of biodiesel from waste cooking oil in a packed-bed reactor: an engineering approach to separation of hydrophilic impurities. Bioresource Technology. ,vol. 135, pp. 417- 421 ,(2013) , 10.1016/J.BIORTECH.2012.06.059

Gulay Bayramoglu, Bunyamin Karagoz, Begum Altintas, M. Yakup Arica, Niyazi Bicak, Poly(styrene–divinylbenzene) beads surface functionalized with di-block polymer grafting and multi-modal ligand attachment: performance of reversibly immobilized lipase in ester synthesis Bioprocess and Biosystems Engineering. ,vol. 34, pp. 735- 746 ,(2011) , 10.1007/S00449-011-0523-1

Mohamad Faiz Mukhtar Gunam Resul, Tinia Idaty Mohd. Ghazi, Azni Idris, Kinetic study of jatropha biolubricant from transesterification of jatropha curcas oil with trimethylolpropane: Effects of temperature Industrial Crops and Products. ,vol. 38, pp. 87- 92 ,(2012) , 10.1016/J.INDCROP.2012.01.012

Ganapati D. Yadav, Shrikant B. Dhoot, Immobilized lipase-catalysed synthesis of cinnamyl laurate in non-aqueous media Journal of Molecular Catalysis B-enzymatic. ,vol. 57, pp. 34- 39 ,(2009) , 10.1016/J.MOLCATB.2008.06.013

Erika CG Aguieiras, Elisa D Cavalcanti-Oliveira, Aline M de Castro, Marta AP Langone, Denise MG Freire, None, Biodiesel production from Acrocomia aculeata acid oil by (enzyme/enzyme) hydroesterification process: Use of vegetable lipase and fermented solid as low-cost biocatalysts Fuel. ,vol. 135, pp. 315- 321 ,(2014) , 10.1016/J.FUEL.2014.06.069

K. Ramani, L. John Kennedy, M. Ramakrishnan, G. Sekaran, Purification, characterization and application of acidic lipase from Pseudomonas gessardii using beef tallow as a substrate for fats and oil hydrolysis. Process Biochemistry. ,vol. 45, pp. 1683- 1691 ,(2010) , 10.1016/J.PROCBIO.2010.06.023

10.

Joab Sampaio de Sousa, Elisa d’Avila Cavalcanti-Oliveira, Donato Alexandre Gomes Aranda, Denise Maria Guimarães Freire, Application of lipase from the physic nut (Jatropha curcas L.) to a new hybrid (enzyme/chemical) hydroesterification process for biodiesel production Journal of Molecular Catalysis B-enzymatic. ,vol. 65, pp. 133- 137 ,(2010) , 10.1016/J.MOLCATB.2010.01.003

Production of alkyl esters from macaw palm oil by a sequential hydrolysis/esterification process using heterogeneous biocatalysts: optimization by response surface methodology.

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Production of alkyl esters from macaw palm oil by a sequential hydrolysis/esterification process using heterogeneous biocatalysts: optimization by response surface methodology.

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