Fuel effects on start-up energy and efficiency for automotive PEM fuel cell systems

作者: T SEMELSBERGER , R BORUP

DOI: 10.1016/J.IJHYDENE.2004.11.007

关键词:

摘要: Abstract This paper investigates the effects of various fuels on hydrogen production for automotive PEM fuel cell systems. Gasoline, methanol, ethanol, dimethyl ether and methane are compared their processor size, start-up energy overall efficiencies 50 kWe processors. The is required to raise temperature from ambient (20 °C) that steady-state operating temperatures. modeled consisted an equilibrium-ATR (autothermal), high-temperature water gas shift (HTS), low-temperature (LTS) preferential oxidation (PrOx) reactors. individual reactor volumes with methane, ether, methanol ethanol were scaled relative a gasoline-fueled meeting 2010 DOE technical targets. were, 25.9 L 30.8 L 42.5 L gasoline, 43.7 L 45.8 L methane. calculated energies 2712 kJ 3423 kJ 6632 kJ 7068 kJ gasoline 7592 kJ efficiencies, correcting using drive cycle 33 miles driven per day, 38.5% 38.3% 37% 34.5% 33.2% assuming efficiency 44% each fuel.

参考文章(23)
Hubert Gasteiger, Wolf Vielstich, Arnold Lamm, Handbook of fuel cells : fundamentals technology and applications Wiley. ,(2003)
B. Morton, M. Inbody, L. Brown, R. Borup, FUEL PROCESSING FOR FUEL CELLS: EFFECTS ON CATALYST DURABILITY AND CARBON FORMATION Conference title not supplied, Conference location not supplied, Conference dates not supplied. ,(2001)
R. L. Borup, J. Tafoya, M. A. Inbody, Transient control of carbon monoxide with staged PrOx reactors Submitted to: 224th National Meetig of the American Chemical Society, Boston, MA, August 18-22, 2002. ,(2002)
Jens R. Rostrup-Nielsen, Conversion of hydrocarbons and alcohols for fuel cells Physical Chemistry Chemical Physics. ,vol. 3, pp. 283- 288 ,(2001) , 10.1039/B004660O
Aida Rodrigues, John C Amphlett, Ronald F Mann, Brant A Peppley, Pierre R Roberge, Carbon monoxide poisoning of proton exchange membrane fuel cells International Journal of Energy Research. ,vol. 25, pp. 695- 713 ,(2001) , 10.1002/ER.713
T. E. Springer, T. Rockward, T. A. Zawodzinski, S. Gottesfeld, Model for Polymer Electrolyte Fuel Cell Operation on Reformate Feed: Effects of CO, H;2 Dilution, and High Fuel Utilization Journal of The Electrochemical Society. ,vol. 148, ,(2001) , 10.1149/1.1344516
Dong Ju Moon, K Sreekumar, Sang Deuk Lee, Byung Gwon Lee, Hoon Sik Kim, Studies on gasoline fuel processor system for fuel-cell powered vehicles application Applied Catalysis A: General. ,vol. 215, pp. 1- 9 ,(2001) , 10.1016/S0926-860X(01)00526-9
G. A. Camara, E. A. Ticianelli, S. Mukerjee, S. J. Lee, J. McBreen, The CO Poisoning Mechanism of the Hydrogen Oxidation Reaction in Proton Exchange Membrane Fuel Cells Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1473775