Hydrogenation of CO2 over skeletal copper surfaces containing precipitated ZnO

作者: Liyan Ma

DOI: 10.1023/A:1023540406916

关键词:

摘要: Catalysts have been prepared by precipitating different amounts of ZnO on the surface skeletal copper particles. The precursor catalysts were fully leaching CuAl2 particles with concentrated NaOH solutions in presence and absence sodium chromate. resulting contained zinc oxide concentrations range 0-1.36 mg per m2 catalyst surface.

参考文章(29)
T. Fujitani, T. Matsuda, Y. Kushida, S. Ogihara, T. Uchijima, J. Nakamura, Creation of the active site for methanol synthesis on a Cu/SiO2 catalyst Catalysis Letters. ,vol. 49, pp. 175- 179 ,(1997) , 10.1023/A:1019069708459
I.A. Fisher, H.C. Woo, A.T. Bell, Effects of zirconia promotion on the activity of Cu/SiO2 for methanol synthesis from CO/H2 and CO2/H2 Catalysis Letters. ,vol. 44, pp. 11- 17 ,(1997) , 10.1023/A:1018916806816
G.C. Chinchen, P.J. Denny, J.R. Jennings, M.S. Spencer, K.C. Waugh, Synthesis of Methanol Applied Catalysis. ,vol. 36, pp. 1- 65 ,(1988) , 10.1016/S0166-9834(00)80103-7
J. Nakamura, I. Nakamura, T. Uchijima, T. Watanabe, T. Fujitani, Model studies of methanol synthesis on copper catalysts Studies in Surface Science and Catalysis. ,vol. 101, pp. 1389- 1399 ,(1996) , 10.1016/S0167-2991(96)80351-X
D. Wang, L. Ma, C.J. Jiang, D.L. Trimm, M.S. Wainwright, D.H. Kim, The effect of zinc oxide in Raney copper catalysts on methanol synthesis, water gas shift, and methanol steam reforming reaction Studies in Surface Science and Catalysis. ,vol. 101, pp. 1379- 1387 ,(1996) , 10.1016/S0167-2991(96)80350-8
T. Fujitani, J. Nakamura, The effect of ZnO in methanol synthesis catalysts on Cu dispersion and the specific activity Catalysis Letters. ,vol. 56, pp. 119- 124 ,(1998) , 10.1023/A:1019000927366
J.W. Evans, M.S. Wainwright, A.J. Bridgewater, D.J. Young, On the determination of copper surface area by reaction with nitrous oxide Applied Catalysis. ,vol. 7, pp. 75- 83 ,(1983) , 10.1016/0166-9834(83)80239-5
M.S. Spencer, Role of ZnO in methanol synthesis on copper catalysts Catalysis Letters. ,vol. 50, pp. 37- 40 ,(1998) , 10.1023/A:1019098414820
Alexander Frank . Wells, Structural inorganic chemistry ,(1945)
Yuriko Nitta, Osamu Suwata, Yasuo Ikeda, Yasuaki Okamoto, Toshinobu Imanaka, Copper-zirconia catalysts for methanol synthesis from carbon dioxide : effect of ZnO addition to Cu-ZrO2 catalysts Catalysis Letters. ,vol. 26, pp. 345- 354 ,(1994) , 10.1007/BF00810608