Synthesis of ABC Star-Shaped Copolymers via a Combination of Controlled Polymerization Techniques
作者： Xiao Bing Wang , Peng Fu , Min Ying Liu , Jian Wei Zhang , Qing Xiang Zhao
DOI: 10.4028/WWW.SCIENTIFIC.NET/AMR.311-313.1161
关键词:
摘要: Two kinds of ABC-type miktoarm star copolymers, poly(α-methylstyrene)-poly(ethylene oxide)-poly(ethoxyethyl glycidylether) (PMS-PEO-PEEGE) and poly(α-methylstyrene)-poly(ethylene oxide)-polyglycidol (PMS-PEO-PG), were synthesized via a combination of anionic polymerization with ring-opening polymerization. Firstly, The poly(α-methyl styryl lithium) (PMS－Li+) was capped by EEGE to form the functionalized poly(α-methylstyrene) with both an active ω-hydroxyl group and an ω’-ethoxyethyl-protected hydroxyl group. Secondly, the PMS-b-PEO block copolymers, star(PMS-PEO-PEEGE) and star(PMS-PEO-PG) copolymers were obtained by the ring-opening polymerization of EO and EEGE via the variation of the functional end group, respectively. Finally, the ethoxyethyl group on the PEEGE arm was hydrolyzed. The obtained miktoarm star copolymers and intermediates were characterized by proton nuclear magnetic resonance (1H-NMR) and size exclusion chromatography (SEC).
sci-hub.se 参考文章(18)
Raju Francis, Daniel Taton, Jennifer L. Logan, Pascal Masse, Yves Gnanou, Randolph S. Duran, Synthesis and Surface Properties of Amphiphilic Star-Shaped and Dendrimer-like Copolymers Based on Polystyrene Core and Poly(ethylene oxide) Corona Macromolecules. ,vol. 36, pp. 8253- 8259 ,(2003) , 10.1021/MA030258K
Olivier Lambert, Simone Reutenauer, Guy Hurtrez, Philippe Dumas, Synthesis of three‐arm star block copolymers Macromolecular Symposia. ,vol. 161, pp. 97- 102 ,(2000) , 10.1002/1521-3900(200010)161:1<97::AID-MASY97>3.0.CO;2-8
Juan Huang, Zhongyu Li, Xuewei Xu, Yong Ren, Junlian Huang, Preparation of novel poly(ethylene oxide‐co‐glycidol)‐graft‐poly(ε‐caprolactone) copolymers and inclusion complexation of the grafted chains with α‐cyclodextrin Journal of Polymer Science Part A. ,vol. 44, pp. 3684- 3691 ,(2006) , 10.1002/POLA.21480
Marc Hans, Peter Gasteier, Helmut Keul, Martin Moeller, Ring-Opening Polymerization of ε-Caprolactone by Means of Mono- and Multifunctional Initiators: Comparison of Chemical and Enzymatic Catalysis Macromolecules. ,vol. 39, pp. 3184- 3193 ,(2006) , 10.1021/MA052657G
Roderic P. Quirk, Gilda M. Lizárraga, Investigation of the Reaction of Poly(styryl)lithium with Propylene Oxide Macromolecules. ,vol. 31, pp. 3424- 3430 ,(1998) , 10.1021/MA980129H
Nikos Hadjichristidis, Marinos Pitsikalis, Stergios Pispas, Hermis Iatrou, Polymers with Complex Architecture by Living Anionic Polymerization Chemical Reviews. ,vol. 101, pp. 3747- 3792 ,(2001) , 10.1021/CR9901337
Stéphanie Angot, K. Shanmugananda Murthy, Daniel Taton, Yves Gnanou, Atom transfer radical polymerization of styrene using a novel octafunctional initiator : Synthesis of well-defined polystyrene stars Macromolecules. ,vol. 31, pp. 7218- 7225 ,(1998) , 10.1021/MA980712Y
Daniel Taton, Alain Le Borgne, Maurice Sepulchre, Nicolas Spassky, Synthesis of chiral and racemic functional polymers from glycidol and thioglycidol Macromolecular Chemistry and Physics. ,vol. 195, pp. 139- 148 ,(1994) , 10.1002/MACP.1994.021950111
Kazuhiro Yamauchi, Keiko Takahashi, Hirokazu Hasegawa, Hermis Iatrou, Nikos Hadjichristidis, Takeshi Kaneko, Yukihiro Nishikawa, Hiroshi Jinnai, Toshimitsu Matsui, Hideo Nishioka, Miyoko Shimizu, Hiromitsu Furukawa, Microdomain Morphology in an ABC 3-Miktoarm Star Terpolymer: A Study by Energy-Filtering TEM and 3D Electron Tomography Macromolecules. ,vol. 36, pp. 6962- 6966 ,(2003) , 10.1021/MA034840K
Laurent Vonna, Hamidou Haidara, Jacques Schultz, Singularity of Polystyrene Chains as the Hydrophobic Group of Amphiphilic Copolymers in Competitive Adsorption Processes: A Comparative Study of Polystyrene−Poly(ethylene oxide) and Poly(dimethyl siloxane)−Poly(ethylene oxide) Block Copolymers Macromolecules. ,vol. 33, pp. 4193- 4197 ,(2000) , 10.1021/MA991299C