作者: Xiuru Xue , Zhaohui Zhao , Yanhua Wang
DOI: 10.1039/C8QO01011K
关键词:
摘要: A chiral Ir–Rh bimetallic nanocatalyst was synthesized and applied in the asymmetric hydrogenation of activated ketones to secondary alcohols with up >99% ee, even a scale-up reaction. More importantly, catalyst could be reused 6 times no loss catalytic performance metal leaching. Remarkably, effect molar ratio Ir Rh is very significant.