Development of a simple spectrophotometric method to estimate uranium concentration in LiCl–KCl matrix

作者: Satendra Kumar , S. Maji , K. Sundararajan , K. Sankaran

DOI: 10.1007/S10967-019-06471-3

关键词:

摘要: A fast, precise and simple spectrophotometric method was developed for the estimation of uranium in LiCl–KCl salt matrix using phosphoric acid as a complexing agent. The 421 nm absorbance peak found to be spectral interference free area this used quantitative analysis. Linearity over 100–7000 ppm with detection limit 25 ppm 10% obtained by method. present successfully applied synthetic mixtures results were more accurate than values measured ICP-OES.

参考文章(40)
P. D. B. Sonali, K. Ajay, J. R. Priyanka, K. Rupali, V. K. Rajesh, S. Rajvir, K. S. Pradeepkumar, Comparison of radiometric and non-radiometric methods for uranium determination in groundwater of Punjab, India Journal of Radioanalytical and Nuclear Chemistry. ,vol. 307, pp. 395- 405 ,(2016) , 10.1007/S10967-015-4132-3
Damien Hudry, Isabelle Bardez, Aydar Rakhmatullin, Catherine Bessada, Florence Bart, Stéphane Jobic, Philippe Deniard, Synthesis of rare earth phosphates in molten LiCl–KCl eutectic: Application to preliminary treatment of chlorinated waste streams containing fission products Journal of Nuclear Materials. ,vol. 381, pp. 284- 289 ,(2008) , 10.1016/J.JNUCMAT.2008.09.005
Linfeng Rao, Guoxin Tian, Thermodynamic study of the complexation of uranium(VI) with nitrate at variable temperatures The Journal of Chemical Thermodynamics. ,vol. 40, pp. 1001- 1006 ,(2008) , 10.1016/J.JCT.2008.02.013
Kelly Servaes, Christoph Hennig, Isabelle Billard, Clotilde Gaillard, Koen Binnemans, Christiane Görller-Walrand, Rik Van Deun, Speciation of Uranyl Nitrato Complexes in Acetonitrile and in the Ionic Liquid 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide European Journal of Inorganic Chemistry. ,vol. 2007, pp. 5120- 5126 ,(2007) , 10.1002/EJIC.200700475
H.C. Eun, J.H. Kim, Y.Z. Cho, J.H. Choi, T.K. Lee, H.S. Park, G.I. Park, An optimal method for phosphorylation of rare earth chlorides in LiCl-KCl eutectic based waste salt Journal of Nuclear Materials. ,vol. 442, pp. 175- 178 ,(2013) , 10.1016/J.JNUCMAT.2013.08.021
Peter Nockemann, Rik Van Deun, Ben Thijs, Diederik Huys, Evert Vanecht, Kristof Van Hecke, Luc Van Meervelt, Koen Binnemans, Uranyl Complexes of Carboxyl-Functionalized Ionic Liquids Inorganic Chemistry. ,vol. 49, pp. 3351- 3360 ,(2010) , 10.1021/IC902406H
Ali Niazi, Neda Khorshidi, Pegah Ghaemmaghami, Microwave-assisted of dispersive liquid–liquid microextraction and spectrophotometric determination of uranium after optimization based on Box–Behnken design and chemometrics methods Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 135, pp. 69- 75 ,(2015) , 10.1016/J.SAA.2014.06.148
Sandy De Houwer, Christiane Görller-Walrand, Influence of complex formation on the electronic structure of uranyl Journal of Alloys and Compounds. ,vol. 323, pp. 683- 687 ,(2001) , 10.1016/S0925-8388(01)01089-1