Electron transfer reduction of a highly electron-deficient fullerene, C60F18.
作者： Kei Ohkubo , Roger Taylor , Olga V. Boltalina , Seiji Ogo , Shunichi Fukuzumi
DOI: 10.1039/B205642A
关键词:
摘要: Electron transfer reduction of a highly electron-deficient fullerene, C60F18, to the defluorinated anion, C60F17− occurs efficiently by relatively weak one-electron reductant, p-chloranil radical anion; potential C60F18 is evaluated as 0.04 V (vs. SCE) comparison rate constant for electron-transfer from 10,10′-dimethyl-9,9′,10,10′-tetrahydro-9,9′-biacridine with those other reductants.
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sci-hub.se 参考文章(10)
Feimeng Zhou, Gary J. Van Berkel, Bernadette T. Donovan, Electron-Transfer Reactions of fluorofullerene C60F48 Journal of the American Chemical Society. ,vol. 116, pp. 5485- 5486 ,(1994) , 10.1021/JA00091A069
Ning Liu, Yasunari Morio, Fujio Okino, Hidekazu Touhara, Olga V. Boltalina, Valeria K. Pavlovich, Electrochemical properties of C60F36 Synthetic Metals. ,vol. 86, pp. 2289- 2290 ,(1997) , 10.1016/S0379-6779(97)81130-7
Shunichi Fukuzumi, Tomohiro Yorisue, Electron-Transfer Reactions from Hydroquinone Dianions to 10-Methylacridinium Ion and a Cobalt(III) Porphyrin Bulletin of the Chemical Society of Japan. ,vol. 65, pp. 715- 719 ,(1992) , 10.1246/BCSJ.65.715
Shunichi Fukuzumi, Tomoyoshi Suenobu, Xiang Gao, Karl M. Kadish, Splitting of Degenerate Orbitals of Dibenzyl and Tetrabenzyl Adducts of C60: ESR of the Radical Anions and the Rotation Barriers of Benzyl Groups Journal of Physical Chemistry A. ,vol. 104, pp. 2908- 2913 ,(2000) , 10.1021/JP993899J
Shunichi Fukuzumi, Tomoyoshi Suenobu, Matthias Patz, Takeomi Hirasaka, Shinobu Itoh, Mamoru Fujitsuka, Osamu Ito, Selective One-Electron and Two-Electron Reduction of C60 with NADH and NAD Dimer Analogues via Photoinduced Electron Transfer Journal of the American Chemical Society. ,vol. 120, pp. 8060- 8068 ,(1998) , 10.1021/JA9813459
Ivan S Neretin, Konstantin A Lyssenko, Mikhail Yu Antipin, Yuri L Slovokhotov, Olga V Boltalina, Pavel A Troshin, Andrei Yu Lukonin, Lev N Sidorov, Roger Taylor, None, C60F18, a Flattened Fullerene: Alias a Hexa-Substituted Benzene Angewandte Chemie. ,vol. 39, pp. 3273- 3276 ,(2000) , 10.1002/1521-3773(20000915)39:18<3273::AID-ANIE3273>3.0.CO;2-F
Shunichi Fukuzumi, Kei Ohkubo, Junzo Otera, Comparison between electron transfer and nucleophilic reactivities of ketene silyl acetals with cationic electrophiles. Journal of Organic Chemistry. ,vol. 66, pp. 1450- 1454 ,(2001) , 10.1021/JO005733G
Yukihiro Yoshida, Akihiro Otsuka, Olga O. Drozdova, Gunzi Saito, Reactivity of C60Cl6 and C60Brn (n = 6, 8) in Solution in the Absence and in the Presence of Electron Donor Molecules Journal of the American Chemical Society. ,vol. 122, pp. 7244- 7251 ,(2000) , 10.1021/JA0005744
Shunichi Fukuzumi, Ikuo Nakanishi, Tomoyoshi Suenobu, Karl M. Kadish, ELECTRON-TRANSFER PROPERTIES OF C60 AND TERT-BUTYL-C60 RADICAL Journal of the American Chemical Society. ,vol. 121, pp. 3468- 3474 ,(1999) , 10.1021/JA9838615
Shunichi Fukuzumi, Yoshihiro Tokuda, Outer-sphere electron-transfer oxidation of 10,10'-dimethyl-9,9',10,10'-tetrahydro-9,9'-biacridine The Journal of Physical Chemistry. ,vol. 96, pp. 8409- 8413 ,(1992) , 10.1021/J100200A037