Supercritical fluid extraction of carqueja (Baccharis trimera) oil: Process parameters and composition profiles

作者: Danielle C.M.N. Silva , Louisiane F.V. Bresciani , Rosenir L. Dalagnol , Leandro Danielski , Rosendo A. Yunes

DOI: 10.1016/J.FBP.2009.01.001

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摘要: Abstract Carqueja ( Baccharis trimer a Less) is common plant native from South America. In this work, the global yield X 0 ) of carqueja oil, extracted by means supercritical CO 2 at 30 and 40 °C 100 to 300 bar, was investigated. The maximum solvent flow rate employed 8.33 gCO /min, with extraction times up 6 h. yields varied 0.34 2.07% (w/w). Additionally, process compared organic in terms oil composition profile. extracts were analyzed gas chromatography–mass spectrometry (GC–MS) 14 different components identified. mathematical models proposed Tan Liou [Tan, C. Liou, D., 1989, Modeling desorption conditions, AIChE J, 35(6): 1029–1031], Brunner [Brunner, G., 1994, Gas Extraction: An Introduction Fundamentals Supercritical Fluids Application Separation Processes (Springer, New York)], Sovova [Sovova, H., Rate vegetable . Modelling curves, Chem Eng Sci, 49(3): 409–414] Esquivel et al. [Esquivel, M.M., Bernardo-Gil, M.G. King, M.B., 1999, Mathematical for olive husk J Fluids, 16: 43–58] used description kinetic aspects process. modeled results showed good agreement experimental data especially constant period (CER).

参考文章(23)
B. Armstrong, S. Angus, K.M. de Reuck, International thermodynamic tables of the fluid state. 5. Methane Pergamon Press Inc.,Elmsford, NY. ,(1978)
Ana H. Januário, Simone L. Santos, Silvana Marcussi, Maurício V. Mazzi, Rosemeire C.L.R. Pietro, Daisy N. Sato, Javier Ellena, Suely V. Sampaio, Suzelei C. França, Andreimar M. Soares, Neo-clerodane diterpenoid, a new metalloprotease snake venom inhibitor from Baccharis trimera (Asteraceae): anti-proteolytic and anti-hemorrhagic properties. Chemico-Biological Interactions. ,vol. 150, pp. 243- 251 ,(2004) , 10.1016/J.CBI.2004.09.016
M.D Gordillo, M.A Blanco, A Molero, E Martinez de la Ossa, Solubility of the antibiotic Penicillin G in supercritical carbon dioxide The Journal of Supercritical Fluids. ,vol. 15, pp. 183- 190 ,(1999) , 10.1016/S0896-8446(99)00008-X
Chung-Sung Tan, Din-Chung Liou, Modeling of desorption at supercritical conditions Aiche Journal. ,vol. 35, pp. 1029- 1031 ,(1989) , 10.1002/AIC.690350616
Antônio Carlos P Oliveira, Denise C Endringer, Luiz Alberto S Amorim, L Brandão Maria das Graças, Márcio M Coelho, None, Effect of the extracts and fractions of Baccharis trimera and Syzygium cumini on glycaemia of diabetic and non-diabetic mice. Journal of Ethnopharmacology. ,vol. 102, pp. 465- 469 ,(2005) , 10.1016/J.JEP.2005.06.025
M.M. Esquı́vel, M.G. Bernardo-Gil, M.B. King, Mathematical models for supercritical extraction of olive husk oil The Journal of Supercritical Fluids. ,vol. 16, pp. 43- 58 ,(1999) , 10.1016/S0896-8446(99)00014-5
Tatiana de S. Weinhold, Louisiane F.V. Bresciani, Cláudia W. Tridapalli, Rosendo A. Yunes, Haiko Hense, Sandra R.S. Ferreira, Polygala cyparissias oleoresin: Comparing CO2 and classical organic solvent extractions Chemical Engineering and Processing: Process Intensification. ,vol. 47, pp. 109- 117 ,(2008) , 10.1016/J.CEP.2007.08.007
H.K Kiriamiti, E Rascol, A Marty, J.S Condoret, Extraction rates of oil from high oleic sunflower seeds with supercritical carbon dioxide Chemical Engineering and Processing. ,vol. 41, pp. 711- 718 ,(2002) , 10.1016/S0255-2701(01)00191-X