A 3D hierarchical assembly of optimized heterogeneous carbon nanosheets for highly efficient electrocatalysis

作者: Gang Wan , Ming Ma , Alec (Yi) Jia , Lisong Chen , Yu Chen

DOI: 10.1039/C6TA03930H

关键词:

摘要: A 3D assembly of crumpled nitrogen-doped carbon nanosheets with hierarchical frameworks and encased ultrafine iron carbide nanoparticles on the subunits was constructed via a template-free bottom-up self-assembly strategy. The optimized structure design catalytic-site integration endow electrocatalyst outstanding PH-universal ORR performance, serving as good alternative for Pt/C catalyst.

参考文章(51)
Andrea Zitolo, Vincent Goellner, Vanessa Armel, Moulay-Tahar Sougrati, Tzonka Mineva, Lorenzo Stievano, Emiliano Fonda, Frédéric Jaouen, Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials. Nature Materials. ,vol. 14, pp. 937- 942 ,(2015) , 10.1038/NMAT4367
Jingjing Duan, Sheng Chen, Mietek Jaroniec, Shi Zhang Qiao, Heteroatom-Doped Graphene-Based Materials for Energy-Relevant Electrocatalytic Processes ACS Catalysis. ,vol. 5, pp. 5207- 5234 ,(2015) , 10.1021/ACSCATAL.5B00991
Stephanie-Angelika Wohlgemuth, Tim-Patrick Fellinger, Philipp Jäker, Markus Antonietti, Tunable nitrogen-doped carbon aerogels as sustainable electrocatalysts in the oxygen reduction reaction Journal of Materials Chemistry. ,vol. 1, pp. 4002- 4009 ,(2013) , 10.1039/C3TA10352H
In-Yup Jeon, Hyun-Jung Choi, Sun-Min Jung, Jeong-Min Seo, Min-Jung Kim, Liming Dai, Jong-Beom Baek, Large-Scale Production of Edge-Selectively Functionalized Graphene Nanoplatelets via Ball Milling and Their Use as Metal-Free Electrocatalysts for Oxygen Reduction Reaction Journal of the American Chemical Society. ,vol. 135, pp. 1386- 1393 ,(2013) , 10.1021/JA3091643
Yibing Li, Haimin Zhang, Yun Wang, Porun Liu, Huagui Yang, Xiangdong Yao, Dan Wang, Zhiyong Tang, Huijun Zhao, A self-sponsored doping approach for controllable synthesis of S and N co-doped trimodal-porous structured graphitic carbon electrocatalysts Energy and Environmental Science. ,vol. 7, pp. 3720- 3726 ,(2014) , 10.1039/C4EE01779J
Yan Jiao, Yao Zheng, Mietek Jaroniec, Shi Zhang Qiao, Origin of the electrocatalytic oxygen reduction activity of graphene-based catalysts: a roadmap to achieve the best performance. Journal of the American Chemical Society. ,vol. 136, pp. 4394- 4403 ,(2014) , 10.1021/JA500432H
Shuangyin Wang, Dingshan Yu, Liming Dai, Dong Wook Chang, Jong-Beom Baek, Polyelectrolyte-Functionalized Graphene as Metal-Free Electrocatalysts for Oxygen Reduction ACS Nano. ,vol. 5, pp. 6202- 6209 ,(2011) , 10.1021/NN200879H
Yin Fang, Yingying Lv, Renchao Che, Haoyu Wu, Xuehua Zhang, Dong Gu, Gengfeng Zheng, Dongyuan Zhao, Two-dimensional mesoporous carbon nanosheets and their derived graphene nanosheets: synthesis and efficient lithium ion storage. Journal of the American Chemical Society. ,vol. 135, pp. 1524- 1530 ,(2013) , 10.1021/JA310849C
Wenxiu Yang, Xiangjian Liu, Xiaoyu Yue, Jianbo Jia, Shaojun Guo, Bamboo-like Carbon Nanotube/Fe3C Nanoparticle Hybrids and Their Highly Efficient Catalysis for Oxygen Reduction Journal of the American Chemical Society. ,vol. 137, pp. 1436- 1439 ,(2015) , 10.1021/JA5129132