Quenching of the Triplet State of Benzophenone by Lanthanide 1,3-Diketonate Chelates in Solutions

作者: Bronislaw Marciniak , Marian Elbanowski , Stefan Lis

DOI: 10.1007/BF00809679

关键词:

摘要: The phosphorescence of benzophenone in benzene and acetonitrile was quenched by several lanthanide (Sm, Eu, Gd, Tb Dy) acetylacetonate chelates. results ofStern-Volmer analysis including the quenching triplet sensitization emission indicate that process occurs energy transfer mechanism via excited state ligand.

参考文章(15)
Nicholas J. Turro, Modern Molecular Photochemistry ,(1978)
Steven L. Murov, Handbook of photochemistry ,(1973)
Tomiki Ikeda, Hitoshi Yamaoka, Tomochika Matsuyama, Seizo Okamura, Photo- and radiation-induced degradation of vinyl polymers in solution. 3. Transient species during photosensitized degradation of poly(.alpha.-methylstyrene) by benzophenone The Journal of Physical Chemistry. ,vol. 82, pp. 2329- 2334 ,(1978) , 10.1021/J100510A017
George S. Hammond, Robert P. Foss, Mechanisms of Photoreactions in Solution. XX.1 Quenching of Excited States of Benzophenone by Metal Chelates The Journal of Physical Chemistry. ,vol. 68, pp. 3739- 3746 ,(1964) , 10.1021/J100794A034
Janet B. Ersts, Michael J. Pilling, Temperature dependence of the rate of deactivation of triplet anthracene by metal ions Journal of the Chemical Society, Faraday Transactions. ,vol. 74, pp. 1403- 1406 ,(1978) , 10.1039/F29787401403
M. L. Bhaumik, M. A. El‐Sayed, Mechanism and Rate of the Intramolecular Energy Transfer Process in Rare‐Earth Chelates The Journal of Chemical Physics. ,vol. 42, pp. 787- 788 ,(1965) , 10.1063/1.1696007
W. F. Sager, N. Filipescu, F. A. Serafin, Substituent Effects on Intramolecular Energy Transfer. I. Absorption and Phosphorescence Spectra of Rare Earth β-Diketone Chelates The Journal of Physical Chemistry. ,vol. 69, pp. 1092- 1100 ,(1965) , 10.1021/J100888A002
Yoshihisa Matsuda, Shoji Makishima, Shigeo Shionoya, Intramolecular Energy Transfer in Europium Chelates Due to Excitation of the Triplet State Bulletin of the Chemical Society of Japan. ,vol. 41, pp. 1513- 1518 ,(1968) , 10.1246/BCSJ.41.1513
G. D. R. Napier, J. D. Neilson, T. Maurice Shepherd, Intermolecular energy transfer between tris(acetylacetonato)-lanthanoid complexes in n-butanol solution Journal of the Chemical Society, Faraday Transactions 2. ,vol. 71, pp. 1487- 1496 ,(1975) , 10.1039/F29757101487
Franco Scandola, Vincenzo Balzani, Energy-transfer processes of excited states of coordination compounds Journal of Chemical Education. ,vol. 60, pp. 814- ,(1983) , 10.1021/ED060P814