Double Pseudo-Polymeric Gold(III)-Mercury(II) Complexes [Au(S 2 CNR 2 ) 2 ] n X [R 2 = (CH 2 ) 6 , (CH 2 ) 4 O] Containing ([HgCl 3 ] − ) n , [HgCl 4 ] 2− and [Hg 2 Cl 6 ] 2− Anions: Chemisorption Synthesis, Principles of Supramolecular Self-Assembly, and Thermal Behavior

摘要: Novel pseudo-polymeric complexes of gold(III)-mercury(II) with cyclic alkylene dithiocarbamate ligands: ([Au{S2CN(CH2)6}2][HgCl3])n, ([Au{S2CN(CH2)6}2]2[HgCl4]·H2O)n, and ([Au{S2CN(CH2)4O}2]2[Hg2Cl6])n have been obtained structurally characterized. The sophisticated supramolecular structure the compounds is realized due to secondary non-valent Au⋯S interactions includes mononuclear binuclear cations anions as structural units well cationic anionic polymer chains. thermal behavior has studied by means simultaneous analysis. products transformations are reduced elemental gold HgCl2.