作者: Dage Sundholm , Jeppe Olsen
关键词:
摘要: The nuclear quadrupole moments of {sup 33}S and 35}S are studied using numerical multiconfigurational Hartree-Fock (MCHF) calculations on S{sup {minus}}({sup 2}{ital P}{sub 3/2}). A newly developed finite-element MCHF program allowing very large configuration-interaction expansions is used. 3{ital p}{sup 5} valence correlation decreases the electric field gradient with about 12%, but core-valence polarization increases 14% value. final values for become {minus}0.0678(13) 0.0471(9) b, respectively.