The rotational spectrum and molecular properties of bromine dioxide, OBrO
作者： Holger SP Müller , Charles E Miller , Edward A Cohen , None
DOI: 10.1063/1.475030
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摘要: The rotational spectrum of the OBrO radical has been observed in gas phase over solid products O+Br2 reaction. Spectra have measured for both O79BrO and O81BrO their (000), (010), (020) vibrational states selected regions between 88 627 GHz spanning quantum numbers 1⩽N⩽61 0⩽Ka⩽14. spectra are well described by a Hamiltonian which includes centrifugal distortion effects fine hyperfine terms. molecular structure, dipole moment, harmonic force field derived, they, as structure constants, compared with data related molecules electron spin resonance from isolated cryogenic salt matrices.
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sci-hub.se 参考文章(55)
A. Perrin, J.-M. Flaud, C. Camy-Peyret, B. Carli, M. Carlotti, The far infrared spectrum of 14N16O2 Molecular Physics. ,vol. 63, pp. 791- 810 ,(1988) , 10.1080/00268978800100571
Masazumi Tanoura, Kazuko Chiba, Keiichi Tanaka, Takehiko Tanaka, Microwave spectroscopy of chlorine dioxide: Centrifugal distortion, spin-rotation interaction, and hyperfine interaction constants of 35ClO2 and 37ClO2 Journal of Molecular Spectroscopy. ,vol. 95, pp. 157- 181 ,(1982) , 10.1016/0022-2852(82)90245-4
E.A. Alekseev, S.F. Dyubko, V.V. Ilyushin, S.V. Podnos, The High-Precision Millimeter-Wave Spectrum of32SO2,32SO2(ν2), and34SO2 Journal of Molecular Spectroscopy. ,vol. 176, pp. 316- 320 ,(1996) , 10.1006/JMSP.1996.0092
Charles E Miller, Scott L Nickolaisen, Joseph S Francisco, Stanley P Sander, None, The OBrO C(2A2)←X(2B1) absorption spectrum Journal of Chemical Physics. ,vol. 107, pp. 2300- 2307 ,(1997) , 10.1063/1.474606
Eizi Hirota, High-Resolution Spectroscopy of Transient Molecules ,(1985)
D. Patel, D. Margolese, T. R. Dykea), Electric dipole moment of SO2 in ground and excited vibrational states Journal of Chemical Physics. ,vol. 70, pp. 2740- 2747 ,(1979) , 10.1063/1.437860
A.R.W McKellar, Laser magnetic resonance spectrum of BrO () Journal of Molecular Spectroscopy. ,vol. 86, pp. 43- 54 ,(1981) , 10.1016/0022-2852(81)90104-1
A.C. Legon, J.C. Thorn, Equilibrium nuclear quadrupole coupling constants from the rotational spectrum of BrCl: a source of the electric quadrupole moment ratios Q ( 79 Br)/ Q ( 81 Br) and Q ( 35 Cl)/ Q ( 37 Cl) Chemical Physics Letters. ,vol. 215, pp. 554- 560 ,(1993) , 10.1016/0009-2614(93)89354-K
L. F. Pacios, P. C. Gómez, Ab InitioStudy of Bromine Dioxides OBrO and BrOO Journal of Physical Chemistry A. ,vol. 101, pp. 1767- 1773 ,(1997) , 10.1021/JP963281Z
Harutoshi Takeo, Eizi Hirota, Yonezo Morino, Equilibrium structure and potential function of selenium dioxide by microwave spectroscopy Journal of Molecular Spectroscopy. ,vol. 34, pp. 370- 382 ,(1970) , 10.1016/0022-2852(70)90020-2