An investigation into the production of chloromethyl furfual from bagasse and bagasse pulp
作者： William Doherty , Joshua Howard
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摘要: There are many attractive alternatives to produce chemicals similar those currently produced from fossil fuel resources. The most viable renewable resource of fixed carbon is biomass. This paper examines processing conditions for the production and recovery furanics bagasse as well pulp. It shown that bio-oil consisting mainly (~84% chloromethly furfural) may be obtained in yields ~78% ~87% by weight pulp respectively using a biphasic acid hydrolysis system. system consists an organic layer dichloroethane aqueous phase concentrated hydrochloric acid. Generally lower impurity content higher cellulose content, yield.
cabdirect.org参考文章(8)
Robert Perlack, Douglas Karlen, Laurence Eaton, Anthony Turhollow, Matt Langholtz, Craig Brandt, Mark Downing, Robin Graham, Lynn Wright, Jacob Kavkewitz, Anna Shamey, Richard Nelson, Bryce Stokes, William Rooney, David Muth, J Richard Hess, Jared Abodeely, Chad Hellwinckel, Danial De La Torre Ugarte, Daniel Yoder, James Lyon, Timothy Rials, Timothy Volk, Thomas Buchholz, Lawrence Abrahamson, Robert Anex, Thomas Voigt, William Berguson, Don Riemenschneider, Jane Johnson, Robert Mitchell, Kenneth Vogel, Edward Richard, John Tatarko, Larry Wagner, Kenneth Skog, Patricia Lebow, Dennis Dykstra, Marilyn Buford, Patrick Miles, D Andrew Scott, James Perdue, Robert Rummer, Jamie Barbour, John Stanturf, David McKeever, Ronald Zalesny, Edmund Gee, P Daniel Cassidy, David Lightle, None, U.S. Billion-ton Update: Biomass Supply for a Bioenergy and Bioproducts Industry MPRA Paper. ,(2011) , 10.2172/1023318
B. Kamm, M. Kamm, Principles of biorefineries. Applied Microbiology and Biotechnology. ,vol. 64, pp. 137- 145 ,(2004) , 10.1007/S00253-003-1537-7
Charles E. Wyman, What is (and is not) vital to advancing cellulosic ethanol. Trends in Biotechnology. ,vol. 25, pp. 153- 157 ,(2007) , 10.1016/J.TIBTECH.2007.02.009
Yun Yu, Xia Lou, Hongwei Wu, Some Recent Advances in Hydrolysis of Biomass in Hot-Compressed Water and Its Comparisons with Other Hydrolysis Methods† Energy & Fuels. ,vol. 22, pp. 46- 60 ,(2008) , 10.1021/EF700292P
Congcong Chi, Zeng Zhang, Hou-min Chang, Hasan Jameel, Determination of Furfural and Hydroxymethylfurfural Formed From Biomass Under Acidic Conditions Journal of Wood Chemistry and Technology. ,vol. 29, pp. 265- 276 ,(2009) , 10.1080/02773810903096025
Mark Mascal, Edward B. Nikitin, Dramatic advancements in the saccharide to 5-(chloromethyl)furfural conversion reaction. Chemsuschem. ,vol. 2, pp. 859- 861 ,(2009) , 10.1002/CSSC.200900136
A. Martinez, M.E. Rodriguez, S.W. York, J.F. Preston, L.O. Ingram, Use of UV absorbance To monitor furans in dilute acid hydrolysates of biomass. Biotechnology Progress. ,vol. 16, pp. 637- 641 ,(2000) , 10.1021/BP0000508
C Scarlata, R Ruiz-Peinado, A. D. Crocker, B Hames, A Sluiter Bh, W. J. Sluiter, Sluiter, D Templaton, Determination of structural carbohydrates and lignin in biomass, Technical Report NREL/TP-510-42618, National Renewable Energy Laboratory, Golden, CO ,(2010)