Enhancement of icephobic properties based on UV-curable fluorosilicone copolymer films
作者： Xiaohui Li , Kaiqiang Zhang , Yunhui Zhao , Kongying Zhu , Xiaoyan Yuan
DOI: 10.1039/C5RA15920B
关键词:
摘要: UV-curable films composed of thiol-terminated fluorosilicone methacrylate triblock copolymers (PDMS-b-(PFMA-SH)2), thiol-functionalized PDMS (PDMS-SH) and octavinyl POSS (OVPOSS) were developed for the purpose icephobic application. The PDMS-b-(PFMA-SH)2 firstly synthesized via reversible addition–fragmentation chain transfer polymerization dodecafluoroheptyl (12FMA) or 2-perfluorooctylethyl (17FMA), followed by thiol-modification end groups. results differential scanning calorimetry X-ray diffraction revealed presence perfluoroalkyl side groups in P17FMA as presented crystalline structure. These endowed P17FMA-containing with higher receding contact angles (100.2–113.5°) compared P12FMA-containing films. In icephobicity investigations prepared films, it was found that rebound impacting droplet influenced angle, surface roughness, temperature film surface. Water droplets could from horizontal tilted (30° 45°) surfaces down to −15 °C, allowing dewetting before water froze, while adhered surfaces. Moreover, ice shear strengths all lower than 210 kPa, only about 15% value on bare aluminum Therefore, be a potential candidate applications.
rsc.org
harvard.edu
sci-hub.se 参考文章(45)
Hideo Nakae, Ryuichi Inui, Yosuke Hirata, Hiroyuki Saito, Effects of surface roughness on wettability Acta Materialia. ,vol. 46, pp. 2313- 2318 ,(1998) , 10.1016/S1359-6454(98)80012-8
Shuqing Yang, Qiang Xia, Lin Zhu, Jian Xue, Qingjun Wang, Qing-min Chen, Research on the icephobic properties of fluoropolymer-based materials Applied Surface Science. ,vol. 257, pp. 4956- 4962 ,(2011) , 10.1016/J.APSUSC.2011.01.003
T Bharathidasan, S Vijay Kumar, MS Bobji, RPS Chakradhar, Bharathibai J Basu, None, Effect of wettability and surface roughness on ice-adhesion strength of hydrophilic, hydrophobic and superhydrophobic surfaces Applied Surface Science. ,vol. 314, pp. 241- 250 ,(2014) , 10.1016/J.APSUSC.2014.06.101
Bo Li, Xiaohui Li, Kaiqiang Zhang, Hui Li, Yunhui Zhao, Lixia Ren, Xiaoyan Yuan, Synthesis of POSS-containing fluorosilicone block copolymers via RAFT polymerization for application as non-wetting coating materials Progress in Organic Coatings. ,vol. 78, pp. 188- 199 ,(2015) , 10.1016/J.PORGCOAT.2014.09.004
Dongmei Yu, Yunhui Zhao, Hui Li, Hengzhi Qi, Bo Li, Xiaoyan Yuan, None, Preparation and evaluation of hydrophobic surfaces of polyacrylate-polydimethylsiloxane copolymers for anti-icing Progress in Organic Coatings. ,vol. 76, pp. 1435- 1444 ,(2013) , 10.1016/J.PORGCOAT.2013.05.036
Tadashi Uragmi, Hiroshi Yamada, Takashi Miyata, Effects of Fluorine-Containing Graft and Block Copolymer Additives on Removal Characteristics of Dilute Benzene in Water by Microphase-Separated Membranes Modified with These Additives Macromolecules. ,vol. 39, pp. 1890- 1897 ,(2006) , 10.1021/MA052302X
Koji Honda, Masamichi Morita, Osami Sakata, Sono Sasaki, Atsushi Takahara, None, Effect of Surface Molecular Aggregation State and Surface Molecular Motion on Wetting Behavior of Water on Poly(fluoroalkyl methacrylate) Thin Films Macromolecules. ,vol. 43, pp. 454- 460 ,(2010) , 10.1021/MA901973T
Maurice L. Wadley, Kevin A. Cavicchi, Synthesis of polydimethylsiloxane‐containing block copolymers via reversible addition fragmentation chain transfer (RAFT) polymerization Journal of Applied Polymer Science. ,vol. 115, pp. 635- 640 ,(2010) , 10.1002/APP.31106
Howard A. Stone, Ice-phobic surfaces that are wet. ACS Nano. ,vol. 6, pp. 6536- 6540 ,(2012) , 10.1021/NN303372Q
Mingjun Niu, Ling He, Junyan Liang, Aizhao Pan, Xiang Zhao, Effect of side chains and solvents on the film surface of linear fluorosilicone pentablock copolymers Progress in Organic Coatings. ,vol. 77, pp. 1603- 1612 ,(2014) , 10.1016/J.PORGCOAT.2014.05.008