New approaches for high energy density lithium-sulfur battery cathodes.

作者: Scott Evers , Linda F. Nazar

DOI: 10.1021/AR3001348

关键词:

摘要: The goal of replacing combustion engines or reducing their use presents a daunting problem for society. Current lithium-ion technologies provide a stepping stone for this dramatic but inevitable change. However, the theoretical gravimetric capacity (∼ 300 mA hg–1) is too low to overcome the problems of limited range in electric vehicles, and their cost is too high to sustain the commercial viability of electrified transportation. Sulfur is the one of the most promising next generation cathode materials. Since the 1960s, researchers have …

参考文章(33)
Linlin Qiu, Shichao Zhang, Lan Zhang, Mingming Sun, Weikun Wang, Preparation and enhanced electrochemical properties of nano-sulfur/poly(pyrrole-co-aniline) cathode material for lithium/sulfur batteries Electrochimica Acta. ,vol. 55, pp. 4632- 4636 ,(2010) , 10.1016/J.ELECTACTA.2010.03.030
Rezan Demir-Cakan, Mathieu Morcrette, Farid Nouar, Carine Davoisne, Thomas Devic, Danielle Gonbeau, Robert Dominko, Christian Serre, Gérard Férey, Jean-Marie Tarascon, None, Cathode Composites for Li–S Batteries via the Use of Oxygenated Porous Architectures Journal of the American Chemical Society. ,vol. 133, pp. 16154- 16160 ,(2011) , 10.1021/JA2062659
Lifen Xiao, Yuliang Cao, Jie Xiao, Birgit Schwenzer, Mark H. Engelhard, Laxmikant V. Saraf, Zimin Nie, Gregory J. Exarhos, Jun Liu, A Soft Approach to Encapsulate Sulfur: Polyaniline Nanotubes for Lithium‐Sulfur Batteries with Long Cycle Life Advanced Materials. ,vol. 24, pp. 1176- 1181 ,(2012) , 10.1002/ADMA.201103392
Wook Ahn, Kwang-Bum Kim, Kyu-Nam Jung, Kyoung-Hee Shin, Chang-Soo Jin, Synthesis and electrochemical properties of a sulfur-multi walled carbon nanotubes composite as a cathode material for lithium sulfur batteries Journal of Power Sources. ,vol. 202, pp. 394- 399 ,(2012) , 10.1016/J.JPOWSOUR.2011.11.074
Xiulei Ji, Scott Evers, Robert Black, Linda F. Nazar, Stabilizing lithium-sulphur cathodes using polysulphide reservoirs Nature Communications. ,vol. 2, pp. 325- ,(2011) , 10.1038/NCOMMS1293
Shu-Ru Chen, Yun-Pu Zhai, Gui-Liang Xu, Yan-Xia Jiang, Dong-Yuan Zhao, Jun-Tao Li, Ling Huang, Shi-Gang Sun, Ordered mesoporous carbon/sulfur nanocomposite of high performances as cathode for lithium–sulfur battery Electrochimica Acta. ,vol. 56, pp. 9549- 9555 ,(2011) , 10.1016/J.ELECTACTA.2011.03.005
Guangyuan Zheng, Yuan Yang, Judy J Cha, Seung Sae Hong, Yi Cui, None, Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries Nano Letters. ,vol. 11, pp. 4462- 4467 ,(2011) , 10.1021/NL2027684
Xiulei Ji, Kyu Tae Lee, Linda F. Nazar, A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Nature Materials. ,vol. 8, pp. 500- 506 ,(2009) , 10.1038/NMAT2460
Mumin Rao, Haimei Zheng, Liang Zhang, Yuanchang Li, Wenhui Duan, Jinghua Guo, Elton J. Cairns, Yuegang Zhang, Liwen Ji, Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells Journal of the American Chemical Society. ,vol. 133, pp. 18522- 18525 ,(2012) , 10.1021/JA206955K