Barium ferrite nanoparticles prepared directly by aerosol pyrolysis

作者: T González-Carreño , M.P Morales , C.J Serna

DOI: 10.1016/S0167-577X(99)00238-4

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摘要: BaFe12O19 nanoparticles, 10 nm in diameter, have been obtained by combination of two methods, the citrate precursor and aerosol pyrolysis technique. For first time, well-crystallised barium ferrite particles were an aerosol, produced ultrasonic frequency spraying a iron aqueous solution, tubular furnace at 1000°C, without further heat treatment. The reason why hexaferrite phase forms lower temperatures than other methods is nature solution. particle size was increased up to 100 diameter treatment 1000°C oven. are spherical aggregates 400 nm, which can be easily disaggregated grinding mortar. Changes aggregation state reflected as changes magnetic properties. Saturation magnetisation coercivity values for largest similar those found commercial pigments, 50 emu/g 5600 Oe, respectively.

参考文章(18)
C. D. Graham, B. D. Cullity, Introduction to Magnetic Materials ,(1972)
K. Haneda, A.H. Morrish, Magnetic properties of BaFe/sub 12/O/sub 19/ small particles IEEE Transactions on Magnetics. ,vol. 25, pp. 2597- 2601 ,(1989) , 10.1109/20.24496
O. Kubo, T. Ido, H. Yokoyama, Properties of Ba ferrite particles for perpendicular magnetic recording media IEEE Transactions on Magnetics. ,vol. 18, pp. 1122- 1124 ,(1982) , 10.1109/TMAG.1982.1062007
M.V. Cabañas, J.M. González-Calbet, M. Vallet-Regí, Synthesis of barium hexaferrite by pyrolysis of an aerosol Journal of Materials Research. ,vol. 9, pp. 712- 716 ,(1994) , 10.1557/JMR.1994.0712
Greg A. Ward, Kenneth H. Sandhage, Synthesis of Barium Hexaferrite by the Oxidation of a Metallic Barium–Iron Precursor Journal of the American Ceramic Society. ,vol. 80, pp. 1508- 1516 ,(2005) , 10.1111/J.1151-2916.1997.TB03010.X
Geoffrey Bate, Magnetic recording materials since 1975 Journal of Magnetism and Magnetic Materials. ,vol. 100, pp. 413- 424 ,(1991) , 10.1016/0304-8853(91)90831-T
V.K. Sankaranarayanan, Q.A. Pankhurst, D.P.E. Dickson, C.E. Johnson, Synthesis and characterization of ultrafine lithium ferrite from a citrate precursor Journal of Magnetism and Magnetic Materials. ,vol. 130, pp. 288- 292 ,(1994) , 10.1016/0304-8853(94)90685-8
W. A. Kaczmarek, B. W. Ninham, A. Calka, Structure and magnetic properties of aerosol synthesized barium ferrite particles Journal of Applied Physics. ,vol. 70, pp. 5909- 5911 ,(1991) , 10.1063/1.350103
K. O'Grady, R.L. White, P.J. Grundy, Whither magnetic recording Journal of Magnetism and Magnetic Materials. ,vol. 177, pp. 886- 891 ,(1998) , 10.1016/S0304-8853(97)01048-2
V.K. Sankaranarayanan, D.C. Khan, Mechanism of the formation of nanoscale M-type barium hexaferrite in the citrate precursor method Journal of Magnetism and Magnetic Materials. ,vol. 153, pp. 337- 346 ,(1996) , 10.1016/0304-8853(95)00537-4