Efficient Electrocatalytic Reduction of CO2 by Nitrogen‐Doped Nanoporous Carbon/Carbon Nanotube Membranes: A Step Towards the Electrochemical CO2 Refinery
作者： Hong Wang , Jia Jia , Pengfei Song , Qiang Wang , Debao Li
关键词:
摘要: Herein we introduce a straightforward, low cost, scalable, and technologically relevant method to manufacture an all-carbon, electroactive, nitrogen-doped nanoporous-carbon/carbon-nanotube composite membrane, dubbed “HNCM/CNT”. The membrane is demonstrated function as binder-free, high-performance gas diffusion electrode for the electrocatalytic reduction of CO2 formate. Faradaic efficiency (FE) production formate 81 %. Furthermore, robust structural electrochemical properties endow it with excellent long-term stability.
mpg.de
sci-hub.se 参考文章(58)
Michele Aresta, Carbon dioxide as chemical feedstock Wiley-VCH. ,(2010) , 10.1002/9783527629916
Dunfeng Gao, Hu Zhou, Jing Wang, Shu Miao, Fan Yang, Guoxiong Wang, Jianguo Wang, Xinhe Bao, Size-dependent electrocatalytic reduction of CO2 over Pd nanoparticles. Journal of the American Chemical Society. ,vol. 137, pp. 4288- 4291 ,(2015) , 10.1021/JACS.5B00046
Sebastian Soll, Markus Antonietti, Jiayin Yuan, Double Stimuli-Responsive Copolymer Stabilizers for Multiwalled Carbon Nanotubes ACS Macro Letters. ,vol. 1, pp. 84- 87 ,(2012) , 10.1021/MZ200042H
Jingjie Wu, Ram Manohar Yadav, Mingjie Liu, Pranav P. Sharma, Chandra Sekhar Tiwary, Lulu Ma, Xiaolong Zou, Xiao-Dong Zhou, Boris I. Yakobson, Jun Lou, Pulickel M. Ajayan, Achieving Highly Efficient, Selective, and Stable CO2 Reduction on Nitrogen-Doped Carbon Nanotubes. ACS Nano. ,vol. 9, pp. 5364- 5371 ,(2015) , 10.1021/ACSNANO.5B01079
Quan Shi, Renyuan Zhang, Yingying Lv, Yonghui Deng, Ahmed A. Elzatahrya, Dongyuan Zhao, Nitrogen-doped ordered mesoporous carbons based on cyanamide as the dopant for supercapacitor Carbon. ,vol. 84, pp. 335- 346 ,(2015) , 10.1016/J.CARBON.2014.12.013
Jesse D. Froehlich, Clifford P. Kubiak, Homogeneous CO2 reduction by Ni(cyclam) at a glassy carbon electrode. Inorganic Chemistry. ,vol. 51, pp. 3932- 3934 ,(2012) , 10.1021/IC3001619
Tim-Patrick Fellinger, Arne Thomas, Jiayin Yuan, Markus Antonietti, 25th Anniversary Article: “Cooking Carbon with Salt”: Carbon Materials and Carbonaceous Frameworks from Ionic Liquids and Poly(ionic liquid)s Advanced Materials. ,vol. 25, pp. 5838- 5855 ,(2013) , 10.1002/ADMA.201301975
Xiaowa Nie, Monica R. Esopi, Michael J. Janik, Aravind Asthagiri, Selectivity of CO2 reduction on copper electrodes: The role of the kinetics of elementary steps Angewandte Chemie. ,vol. 52, pp. 2459- 2462 ,(2013) , 10.1002/ANIE.201208320
Mohammad Asadi, Bijandra Kumar, Amirhossein Behranginia, Brian A. Rosen, Artem Baskin, Nikita Repnin, Davide Pisasale, Patrick Phillips, Wei Zhu, Richard Haasch, Robert F. Klie, Petr Král, Jeremiah Abiade, Amin Salehi-Khojin, Robust carbon dioxide reduction on molybdenum disulphide edges Nature Communications. ,vol. 5, pp. 4470- ,(2014) , 10.1038/NCOMMS5470
Cyrille Costentin, Marc Robert, Jean-Michel Savéant, Catalysis of the electrochemical reduction of carbon dioxide Chemical Society Reviews. ,vol. 42, pp. 2423- 2436 ,(2013) , 10.1039/C2CS35360A