ELECTRON TRANSFER REACTIONS OF METAL CARBONYL ANIONS
作者： Jim D. Atwood , M. Shauna Corraine-pandolfino , Yueqian Zhen , William S. Striejewske , C. K. Lai
DOI: 10.1080/00958979408024238
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摘要: Abstract Metal carbonyl anions exhibit one- and two-electron reactions. The processes involving transfer of groups (hydrogen, alkyl, halogen) between metal centers are related to the nucleophilicity. one-electron primarily outer-sphere electron for anions. These reactions observed in presence oxidants such as coordination complexes, pyridinium salts, dimers clusters. However, contrast organic reactions, may undergo inner-sphere transfer. Reactions low nucleophilicity with cations or halides best interpreted inner-sphere,
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