The combustion of simple ketones II—Mechanism at ‘high’ temperatures
作者： D.E. Hoare , Ting-Man Li
DOI: 10.1016/0010-2180(68)90089-8
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摘要: It is shown that the ‘low’ temperature combustion of some simple ketones occurs chiefly by propagation reactions which fall into three categories. The radical RCOCHR' formed removal a hydrogen atom from ketone first adds on oxygen, then at least different take place: Download : full-size image For acetone and diethyl I II are most important but for methyl ethyl (by contrast) reaction III much more than II. A value relative rate constants CH3O+O2 →CH2O2 +HO2and CH3O+CH3COCH3 →CH3OH+CH2COCH3 330°C also reported.
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