Copolymers of 2‐acrylamido‐2‐methylpropanesulfonic acid and aromatic vinyl compounds as potential media for photosensitized electron transfer reactions

摘要: In an expectation as potential media for photosensitized electron transfer reactions, polymers carrying both strong electrolytic and hydrophobic segments were prepared by the copolymerization of 2-acrylamido-2-methylpropanesulfonic acid (AMPS) styrene. The AMPS found to have a remarkable power solubilize into water, i.e., even copolymer with styrene mole fraction 0,72 is still soluble in water. Salt effect on reduced viscosity, broadening NMR spectra D2O, enhanced excimer fluorescence styryl groups aqueous solution indicated pronounced interaction number along chain high content. 8-Anilinonaphthalene-1-sulfonic acid, 1,6-diphenyl-1,3,5-hexatriene, cyanine dye used fluorescent probes microdomains. results suggested that microdomains are highly nature but less capable than surfactant micelles. An microscopic image was also discussed supporting evidence presence