A convenient synthesis and preliminary photophysical study of novel fluoroionophores: macrocyclic polyamines containing two dansylamidoethyl side arms
作者： R.Todd Bronson , Paul B Savage , Kryzsztof E Krakowiak , Reed M Izatt , Luca Prodi
DOI: 10.1016/S0040-4020(00)00999-6
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摘要: Abstract A series of novel fluorophores, consisting macrocyclic polyamines containing two dansylamidoethyl side arms were synthesized as potential zinc (II) fluoroionophores by the reaction appropriate with N-dansylaziridine in acetonitrile at reflux temperature. Preliminary photophysical studies ligand 3a, 1,7-dimethyl-4,10-bis(dansylamidoethyl)-1,4,7,10-tetraazacyclododecane, 3j, 8,13-bis(dansylamidoethyl)-3-hydroxymethyl-1,3,10-trithia-8,13-diazacyclopentadecane, and their complexes Cu2+, Zn2+, Cd2+, Hg2+ are described.
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