A New Method to Elucidate the Mechanism of Heterogeneous Catalysis by Means of Microwave Spectroscopic Techniques

作者: Toshihiko Kondo , Kenzi Tamaru

DOI: 10.1007/978-1-4615-8759-0_29

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摘要: A new method is proposed to identify the intermediates of hydrogen-deuterium exchange reaction propene, namely, microwave spectroscopic techniques which permit determination distribution geometrical isomers propene-d 1 and -d 2 formed during course reaction. This makes it feasible many intermediates, i.e., 1-propyl, 2-propyl, 1-propenyl, 2-propenyl, σ-allyl, π-allyl as well concerted mechanism.

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