Structuralization of Ca2+-Based Metal–Organic Frameworks Prepared via Coordination Replication of Calcium Carbonate
作者： Kenji Sumida , Ming Hu , Shuhei Furukawa , Susumu Kitagawa
DOI: 10.1021/ACS.INORGCHEM.6B00397
关键词:
摘要: The emergence of metal–organic frameworks (MOFs) as potential candidates to supplant existing adsorbent types in real-world applications has led an explosive growth the number compounds available researchers, well diversity metal salts and organic linkers from which they are derived. In this context, use carbonate-based precursors sources is interest due their abundance mineral deposits reaction chemistry with acids, resulting just water carbon dioxide side products. Here, we have explored calcium carbonate a source demonstrate its versatility precursor several known frameworks, new flexible compound based on 2,5-dihydroxybenzoquinone (H2dhbq) linker, Ca(dhbq)(H2O)2. Furthermore, inspired by ubiquity unique structures biomineralized forms carbonate, also present examples preparation superstructures Ca-based MOFs via coordination replication...
acs.org
s3-eu-west-1.amazonaws.com 参考文章(24)
Kenji Sumida, Nirmalya Moitra, Julien Reboul, Shotaro Fukumoto, Kazuki Nakanishi, Kazuyoshi Kanamori, Shuhei Furukawa, Susumu Kitagawa, None, Mesoscopic superstructures of flexible porous coordination polymers synthesized via coordination replication Chemical Science. ,vol. 6, pp. 5938- 5946 ,(2015) , 10.1039/C5SC02034D
Shotaro Fukumoto, Kazuki Nakanishi, Kazuyoshi Kanamori, None, Direct preparation and conversion of copper hydroxide-based monolithic xerogels with hierarchical pores New Journal of Chemistry. ,vol. 39, pp. 6771- 6777 ,(2015) , 10.1039/C5NJ00479A
Julien Reboul, Shuhei Furukawa, Nao Horike, Manuel Tsotsalas, Kenji Hirai, Hiromitsu Uehara, Mio Kondo, Nicolas Louvain, Osami Sakata, Susumu Kitagawa, None, Mesoscopic architectures of porous coordination polymers fabricated by pseudomorphic replication Nature Materials. ,vol. 11, pp. 717- 723 ,(2012) , 10.1038/NMAT3359
Masashi Nakahama, Julien Reboul, Ken-ichiro Kamei, Susumu Kitagawa, Shuhei Furukawa, Fibrous Architectures of Porous Coordination Polymers–Alumina Composites Fabricated by Coordination Replication Chemistry Letters. ,vol. 43, pp. 1052- 1054 ,(2014) , 10.1246/CL.140291
Kim J Yaghi, OM, O'Keeffe, M, Ockwig NW, Chae, HK, Eddaoudi M, Reticular synthesis and the design of new materials Nature. ,vol. 423, pp. 705- 714 ,(2003) , 10.1038/NATURE01650
Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro, Functional Porous Coordination Polymers Angewandte Chemie International Edition. ,vol. 43, pp. 2334- 2375 ,(2004) , 10.1002/ANIE.200300610
T. Matsuzaki, Y. Iitaka, The crystal structure of calcium terephthalate trihydrate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 28, pp. 1977- 1981 ,(1972) , 10.1107/S0567740872005382
Gérard Férey, Hybrid porous solids: past, present, future Chemical Society Reviews. ,vol. 37, pp. 191- 214 ,(2008) , 10.1039/B618320B
Wen-wen Zhan, Qin Kuang, Jian-zhang Zhou, Xiang-jian Kong, Zhao-xiong Xie, Lan-sun Zheng, Semiconductor@Metal–Organic Framework Core–Shell Heterostructures: A Case of ZnO@ZIF-8 Nanorods with Selective Photoelectrochemical Response Journal of the American Chemical Society. ,vol. 135, pp. 1926- 1933 ,(2013) , 10.1021/JA311085E
Christian Robl, Armin Weiss, Alkaline-earth squarates III.CaC4O4 · 2.5H2O, a novel polymer complex with zeolitic properties (1) Materials Research Bulletin. ,vol. 22, pp. 373- 380 ,(1987) , 10.1016/0025-5408(87)90055-9