Nucleophilic and Electrophilic Catalysis with Transition Metal Complexes

作者: Giorgio Strukul

DOI: 10.1007/978-94-017-0984-2_6

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摘要: As outlined in chapter 1 the activation of H2O2 presence transition metal complexes to give peroxo species is one major pathways through which hydrogen peroxide can be employed as primary oxidant for synthesis oxygenated compounds. In this it will discussed how lead having either electrophilic or nucleophilic characteristics and guideline may helpful suggesting appropriate catalyst a given reaction. However, before doing so seems summarize some general physico-chemical features peroxide.

参考文章(151)
Berit F. Pedersen, Bjørn Pedersen, Tore Ledaal, Hans M. Seip, The Crystal Structure of Sodium Oxalate Perhydrate Na2C2O4.H2O2. Acta Chemica Scandinavica. ,vol. 18, pp. 1454- 1468 ,(1964) , 10.3891/ACTA.CHEM.SCAND.18-1454
Antonino Arcoria, Francesco Paolo Ballistreri, Gaetano Andrea Tomaselli, Fulvio Di Furia, Giorgio Modena, The relevance of acid-base equilibria in the catalytic oxidations by tungsten and molybdenum peroxo complexes Journal of Molecular Catalysis. ,vol. 24, pp. 189- 196 ,(1984) , 10.1016/0304-5102(84)85130-5
C. A. Bunton, G. J. Minkoff, 143. The oxidation of αβ-unsaturated ketones with alkaline hydrogen peroxide J. Chem. Soc.. ,vol. 0, pp. 665- 670 ,(1949) , 10.1039/JR9490000665
Giorgio Strukul, Rino A. Michelin, Catalytic epoxidation of 1-octene with diluted hydrogen peroxide. On the basic role of hydroxo complexes of platinum(II) and related species Journal of the American Chemical Society. ,vol. 107, pp. 7563- 7569 ,(1985) , 10.1021/JA00311A056
D. R. C. Huybrechts, L. De Bruycker, P. A. Jacobs, Oxyfunctionalization of alkanes with hydrogen peroxide on titanium silicalite Nature. ,vol. 345, pp. 240- 242 ,(1990) , 10.1038/345240A0
G. Villain, Ph. Kalck, A. Gaset, Regioselective hydration of acrylonitrile to give acrylamide catalyzed by (Pd(OH)2(bipyridine)(H2O)) Tetrahedron Letters. ,vol. 21, pp. 2901- 2904 ,(1980) , 10.1016/S0040-4039(00)78639-4
RA Sheldon, JA Van Doorn, CWA Schram, AJ De Jong, Metal-catalyzed epoxidation of olefins with organic hydroperoxides II. The effect of solvent and hydroperoxide structure Journal of Catalysis. ,vol. 31, pp. 438- 443 ,(1973) , 10.1016/0021-9517(73)90315-1