Determination of tris(4-chlorophenyl)methanol and tris(4-chlorophenyl)methane in fish, marine mammals and sediment.
作者： Jacob de Boer , Peter G. Wester , Erik H.G. Evers , Udo A. Th. Brinkman
DOI: 10.1016/0269-7491(96)00017-6
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摘要: Abstract Tris (4-chlorophenyl)methanol (TCP) and tris (4-chlorophenyl)methane (TCPMe) were determined in aquatic organisms sediment by a method based on Soxhlet extraction, gel permeation chromatography, fractionation over silica gas chromatography/mass spectrometry (GC/MS) analysis. TCPMe was identified as the 4-substituted isomer after synthesis of this compound. TCP could be GC/MS with negative chemical ionistation (GC/NCI-MS) detection limit 0.02 g kg −1 recovery 90%. concentrations marine mammals from North Sea Dutch Wadden ranged 0.2 to 2 mg , those freshwater fish samples 0.005 0.4 lipid wt basis. two Rhine delta 1.2 3.0 μg dry wt, respectively. concentrations, electron impact (GC/EI-MS), 10–50% concentration all analysed.
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Corwin Herman Hansch, Albert Leo, Substituent constants for correlation analysis in chemistry and biology Published in <b>1979</b> in New York NY) by Wiley. ,(1979)
Glenda B. Michaels, David L. Lewis, Sorption and toxicity of azo and triphenylmethane dyes to aquatic microbial populations Environmental Toxicology and Chemistry. ,vol. 4, pp. 45- 50 ,(1985) , 10.1002/ETC.5620040107
E. M. EMMERT, RAPID DETERMINATION OF ORGANIC CARBON IN SOIL Soil Science. ,vol. 46, pp. 397- 400 ,(1938) , 10.1097/00010694-193811000-00005
L.J. Mebius, A rapid method for the determination of organic carbon in soil Analytica Chimica Acta. ,vol. 22, pp. 120- 124 ,(1960) , 10.1016/S0003-2670(00)88254-9
J. de Boer, C.J.N. Stronck, W.A. Traag, J. van der Meer, Non-ortho and mono-ortho substituted chlorobiphenyls and chlorinated dibenzo-p-dioxins and dibenzofurans in marine and freshwater fish and shellfish from The Netherlands Chemosphere. ,vol. 26, pp. 1823- 1842 ,(1993) , 10.1016/0045-6535(93)90077-I
Walter M. Jarman, Mary Simon, Ross J. Norstrom, Stephanie A. Burns, Corinne A. Bacon, Bernd R. T. Simoneit, Robert W. Risebrough, Global distribution of tris(4-chlorophenyl)methanol in high tropic level birds and mammals Environmental Science & Technology. ,vol. 26, pp. 1770- 1774 ,(1992) , 10.1021/ES00033A009
Soren. Jensen, Lars. Renberg, Lars. Reutergardh, Residue analysis of sediment and sewage sludge for organochlorines in the presence of elemental sulfur Analytical Chemistry. ,vol. 49, pp. 316- 318 ,(1977) , 10.1021/AC50010A033
M.S. Rahman, L. Montanarella, B. Johansson, B.R. Larsen, Trace levels of tris(4-chlorophenyl)-methanol and -methane in human milk Chemosphere. ,vol. 27, pp. 1487- 1497 ,(1993) , 10.1016/0045-6535(93)90243-X
Glenda B. Michaels, David L. Lewis, Microbial transformation rates of AZO and triphenylmethane dyes Environmental Toxicology and Chemistry. ,vol. 5, pp. 161- 166 ,(1986) , 10.1002/ETC.5620050206
Hans-Rudolf. Buser, DDT, A Potential Source of Environmental Tris(4-chlorophenyl)methane and Tris(4-chlorophenyl)methanol. Environmental Science & Technology. ,vol. 29, pp. 2133- 2139 ,(1995) , 10.1021/ES00008A036