Interaction of alkanes with unsaturated metal centers. 2. Complexes of alkanes and fluoroalkanes with tungsten pentacarbonyl in the gas phase

作者: Carl E. Brown , Yoichi Ishikawa , Peter A. Hackett , David M. Rayner

DOI: 10.1021/JA00163A008

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摘要: Time-resolved infrared spectroscopy has been used to study the interaction of a range open-chain, cyclic, and fluorine-substituted alkanes with species W(CO) 5 . forms reversible complexes all unsubstituted studied except CH 4

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