Dicyclo-hexyl-ammonium thio-cyanate: monoclinic polymorph.

摘要: The title salt, C12H24N+·NCS−, represents a monoclinic polymorph of the previously reported ortho­rhom­bic form [Khawar Rauf et al. (2008). Acta Cryst. E64, o366]. Two independent formula units comprise asymmetric unit with major difference in their mol­ecular structures relating to relative dispositions cyclo­hexyl rings [dihedral angles = 79.88 (6) and 67.72 (5)°]. Further, anions distinctive patterns hydrogen-bonding inter­actions, i.e. 2 × N—H⋯N versus N—H⋯S. resulting supra­molecular architecture is chain along c axis based on square-wave topology.