Coexistence of inverse and normal magnetocaloric effect in A-site ordered NdBaMn2O6

作者: Q. Zhang , F. Guillou , A. Wahl , Y. Bréard , V. Hardy

DOI: 10.1063/1.3453657

关键词:

摘要: NdBaMn2O6 exhibits a sequence of two following magnetic transitions: second-order paramagnetic-ferromagnetic transition at TC=290 K, followed by first-order ferromagnetic-antiferromagnetic around TN=210 K, leading to normal and inverse magnetocaloric effects (MCE), respectively. For ΔB=5 T, the combined |−ΔSMmax| TC TN is found be 2.5 J/kg K 1.4 J/kgK, Moreover, presence these −ΔSM peaks spanning over broad range temperature leads remarkably wide working region, yielding significant performance in terms refrigerant efficiency. The present study demonstrates that adjusting degree A-site cation ordering perovskite oxides an efficient strategy induce room-temperature MCE.

参考文章(28)
D. Akahoshi, Y. Okimoto, M. Kubota, R. Kumai, T. Arima, Y. Tomioka, Y. Tokura, Charge-orbital ordering near the multicritical point inA-site ordered perovskites SmBaMn2O6andNdBaMn2O6 Physical Review B. ,vol. 70, pp. 064418- ,(2004) , 10.1103/PHYSREVB.70.064418
M K Chattopadhyay, M A Manekar, S B Roy, Magnetocaloric effect in CeFe2 and Ru-doped CeFe2 alloys Journal of Physics D. ,vol. 39, pp. 1006- 1011 ,(2006) , 10.1088/0022-3727/39/6/002
Z. B. Guo, J. R. Zhang, H. Huang, W. P. Ding, Y. W. Du, LARGE MAGNETIC ENTROPY CHANGE IN LA0.75CA0.25MNO3 Applied Physics Letters. ,vol. 70, pp. 904- 905 ,(1997) , 10.1063/1.118309
J. Glanz, Making a Bigger Chill With Magnets Science. ,vol. 279, pp. 2045- 2045 ,(1998) , 10.1126/SCIENCE.279.5359.2045
Manh-Huong Phan, Seong-Cho Yu, Nam Hwi Hur, Excellent magnetocaloric properties of La0.7Ca0.3−xSrxMnO3(0.05⩽x⩽0.25) single crystals Applied Physics Letters. ,vol. 86, pp. 072504- ,(2005) , 10.1063/1.1867564
Q Zhang, J Du, YB Li, NK Sun, WB Cui, D Li, ZD Zhang, None, Magnetic properties and enhanced magnetic refrigeration in (Mn1−xFex)5Ge3 compounds Journal of Applied Physics. ,vol. 101, pp. 123911- ,(2007) , 10.1063/1.2748723
Q Zhang, B Li, XG Zhao, ZD Zhang, None, Magnetic and reversible magnetocaloric properties of (Gd1−xDyx)4Co3 ferrimagnets Journal of Applied Physics. ,vol. 105, pp. 053902- ,(2009) , 10.1063/1.3075627
S. V. Trukhanov, I. O. Troyanchuk, M. Hervieu, H. Szymczak, K. Bärner, Magnetic and electrical properties ofLBaMn2O6−γ(L=Pr,Nd, Sm, Eu, Gd, Tb) manganites Physical Review B. ,vol. 66, ,(2002) , 10.1103/PHYSREVB.66.184424
Zhida Han, Hongliang Wu, Dunhui Wang, Zhenghe Hua, Chengliang Zhang, Benxi Gu, Youwei Du, Coexistence of low-field positive and negative magnetic entropy change in SmMn2Ge2 Journal of Applied Physics. ,vol. 100, pp. 043908- ,(2006) , 10.1063/1.2266036
Tomohiko Nakajima, Hideki Yoshizawa, Yutaka Ueda, Hiroshi Kageyama, Structures and Electromagnetic Properties of New Metal-Ordered Manganites: RBaMn2O6 (R=Y and Rare-Earth Elements). Journal of the Physical Society of Japan. ,vol. 71, pp. 2843- 2846 ,(2002) , 10.1143/JPSJ.71.2843