Photocatalytic properties of hierarchical BiOXs obtained via an ethanol-assisted solvothermal process
作者： Manke Jia , Xiaolong Hu , Shulian Wang , Yingping Huang , Lirong Song
DOI: 10.1016/J.JES.2014.09.045
关键词:
摘要: In this study, bismuth oxyhalide (BiOXs (XCl, Br, I)) semiconductors were prepared by a simple solvothermal method, with ethanol serving as solvent and series of tetrabutylammonium halide surfactants halogen sources. Under identical synthetic conditions, BiOBr was more readily constructed into regular flower-like hierarchical architectures. The photocatalytic properties the materials studied monitoring degradation rhodamine B (RhB), visible light absorption, colorless salicylic acid (SA). It found that both RhB SA rapidly degraded on surface BiOBr. BiOCl rather active for RhB, but ineffective toward SA. However, neither nor could be effectively in case BiOI. Further experiments such UV-visible spectroscopy detection OH O2(-) radicals suggest electronic structure BiOX photocatalysts is responsible difference their activities.
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Xi Zhang, Zhihui Ai, Falong Jia, Lizhi Zhang, Generalized One-Pot Synthesis, Characterization, and Photocatalytic Activity of Hierarchical BiOX (X = Cl, Br, I) Nanoplate Microspheres Journal of Physical Chemistry C. ,vol. 112, pp. 747- 753 ,(2008) , 10.1021/JP077471T
Salman Ahmad Khan, Neha Singh, Kishwar Saleem, Synthesis, characterization and in vitro antibacterial activity of thiourea and urea derivatives of steroids. European Journal of Medicinal Chemistry. ,vol. 43, pp. 2272- 2277 ,(2008) , 10.1016/J.EJMECH.2007.12.012
Xiaoyan Qin, Hefeng Cheng, Wenjun Wang, Baibiao Huang, Xiaoyang Zhang, Ying Dai, Three dimensional BiOX (X=Cl, Br and I) hierarchical architectures: facile ionic liquid-assisted solvothermal synthesis and photocatalysis towards organic dye degradation Materials Letters. ,vol. 100, pp. 285- 288 ,(2013) , 10.1016/J.MATLET.2013.03.045
Jinyan Xiong, Zhengbo Jiao, Gongxuan Lu, Wei Ren, Jinhua Ye, Yingpu Bi, Facile and Rapid Oxidation Fabrication of BiOCl Hierarchical Nanostructures with Enhanced Photocatalytic Properties Chemistry: A European Journal. ,vol. 19, pp. 9472- 9475 ,(2013) , 10.1002/CHEM.201300384
ZhangSheng Liu, BianTao Wu, DongHu Xiang, YaBo Zhu, Effect of solvents on morphology and photocatalytic activity of BiOBr synthesized by solvothermal method Materials Research Bulletin. ,vol. 47, pp. 3753- 3757 ,(2012) , 10.1016/J.MATERRESBULL.2012.06.026
Yinchang Feng, Lei Li, Junwei Li, Junfeng Wang, Lu Liu, Synthesis of mesoporous BiOBr 3D microspheres and their photodecomposition for toluene. Journal of Hazardous Materials. ,vol. 192, pp. 538- 544 ,(2011) , 10.1016/J.JHAZMAT.2011.05.048
Zhengtao Deng, Dong Chen, Bo Peng, Fangqiong Tang, From Bulk Metal Bi to Two-Dimensional Well-Crystallized BiOX (X = Cl, Br) Micro- and Nanostructures: Synthesis and Characterization Crystal Growth & Design. ,vol. 8, pp. 2995- 3003 ,(2008) , 10.1021/CG800116M
Meng Shang, Wenzhong Wang, Ling Zhang, Preparation of BiOBr lamellar structure with high photocatalytic activity by CTAB as Br source and template. Journal of Hazardous Materials. ,vol. 167, pp. 803- 809 ,(2009) , 10.1016/J.JHAZMAT.2009.01.053
Lei Zhang, Xiao-Feng Cao, Xue-Tai Chen, Zi-Ling Xue, BiOBr hierarchical microspheres: Microwave-assisted solvothermal synthesis, strong adsorption and excellent photocatalytic properties Journal of Colloid and Interface Science. ,vol. 354, pp. 630- 636 ,(2011) , 10.1016/J.JCIS.2010.11.042
Xiaofeng Chang, Jun Huang, Cheng Cheng, Qian Sui, Wei Sha, Guangbin Ji, Shubo Deng, Gang Yu, BiOX (X = Cl, Br, I) photocatalysts prepared using NaBiO3 as the Bi source: Characterization and catalytic performance Catalysis Communications. ,vol. 11, pp. 460- 464 ,(2010) , 10.1016/J.CATCOM.2009.11.023