Ionic Liquids as Green Solvents for the Oxidation of Alcohols

作者: Farhad Shirini , Masoumeh Abedini , Seyyed Vahid Atghia , None

DOI: 10.1007/978-94-007-2891-2_14

关键词:

摘要: Carbonyl compounds are of central importance to organic chemistry, biochemistry, and biology. Aldehydes ketones used as starting materials or reagents for the synthesis other compounds, drugs, polymeric products. Out several available methods these oxidation alcohols is most important. In this chapter, we will discuss summarize using different types oxidizing agents and/or systems ionic liquids green solvents. Mild reaction conditions, simple easy work-up procedure, high excellent yields, stability reusability catalyst noteworthy advantages methods.

参考文章(78)
G. Driver, K. E. Johnson, 3-Methylimidazolium bromohydrogenates(I): a room-temperature ionic liquid for ether cleavage Green Chemistry. ,vol. 5, pp. 163- 169 ,(2003) , 10.1039/B211548D
Imtiaz A. Ansari, Rene Gree, TEMPO-Catalyzed Aerobic Oxidation of Alcohols to Aldehydes and Ketones in Ionic Liquid [bmim][PF6] Organic Letters. ,vol. 4, pp. 1507- 1509 ,(2002) , 10.1021/OL025721C
Steven V. Ley, Chandrashekar Ramarao, Martin D. Smith, Tetra-N-propylammonium perruthenate: a case study in catalyst recovery and re-use involving tetraalkylammonium salts. Chemical Communications. pp. 2278- 2279 ,(2001) , 10.1039/B107966M
Abdol Reza Hajipour, Fatemeh Rafiee, Arnold E. Ruoho, Oxidation of Benzylic Alcohols to Their Corresponding Carbonyl Compounds using KIO4 in Ionic Liquid by Microwave Irradiation Synthetic Communications. ,vol. 36, pp. 2563- 2568 ,(2006) , 10.1080/00397910600781539
Ahmad Shaabani, Elham Farhangi, Abbas Rahmati, Aerobic oxidation of alkyl arenes and alcohols using cobalt(II) phthalocyanine as a catalyst in 1-butyl-3-methyl-imidazolium bromide Applied Catalysis A: General. ,vol. 338, pp. 14- 19 ,(2008) , 10.1016/J.APCATA.2007.12.014
Nan Jiang, Arthur J. Ragauskas, Selective aerobic oxidation of activated alcohols into acids or aldehydes in ionic liquids. Journal of Organic Chemistry. ,vol. 72, pp. 7030- 7033 ,(2007) , 10.1021/JO0707737
Ahmad Shaabani, Elham Farhangi, Abbas Rahmati, Ionic liquid promoted selective oxidation of organic compounds with NaBrO3 Monatshefte für Chemie - Chemical Monthly. ,vol. 139, pp. 905- 908 ,(2008) , 10.1007/S00706-007-0840-X
Christian P. Mehnert, Raymond A. Cook, Nicholas C. Dispenziere, Mobae Afeworki, Supported ionic liquid catalysis--a new concept for homogeneous hydroformylation catalysis. Journal of the American Chemical Society. ,vol. 124, pp. 12932- 12933 ,(2002) , 10.1021/JA0279242