Densities and refractive indices of imidazolium- and phosphonium-based ionic liquids: Effect of temperature, alkyl chain length, and anion
作者： M. Tariq , P.A.S. Forte , M.F. Costa Gomes , J.N. Canongia Lopes , L.P.N. Rebelo
DOI: 10.1016/J.JCT.2009.01.012
关键词:
摘要: Abstract A systematic study of densities and refractive indices 17 room temperature ionic liquids is presented at four different temperatures ranging from 293 K to 333 K. The are grouped into families: 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide, [C n mim ][N tf 2 ], (with = 2, 4, 6, 8, 10, 12, 14); hexafluorophosphate, ][PF 6 = 4, 8); based on the trihexyl(tetradecyl)phosphonium cation, [P 14 combined with anions [N acetate, [O Ac triflate, Tf ]; 4 ]-based methylsulfate [ Me SO tetrafluoroborate [BF ]. data obtained were analysed determine effect (i) temperature, (ii) alkyl chain length (iii) nature anion. Different empirical models for calculation tested. Molar refractions also calculated volumetric index values discussed aim checking their utility in obtaining insights intermolecular forces behaviour solution liquids.
elsevier.com
sci-hub.se 参考文章(72)
Begoña García, Rafael Alcalde, Santiago Aparicio, José M. Leal, Volumetric properties, viscosities and refractive indices of binary mixed solvents containing methyl benzoate Phys. Chem. Chem. Phys.. ,vol. 4, pp. 5833- 5840 ,(2002) , 10.1039/B208086A
Ana B. Pereiro, Ana Rodríguez, Thermodynamic Properties of Ionic Liquids in Organic Solvents from (293.15 to 303.15) K Journal of Chemical & Engineering Data. ,vol. 52, pp. 600- 608 ,(2007) , 10.1021/JE060497D
Jessica L. Anderson, JaNeille K. Dixon, Joan F. Brennecke, Solubility of CO2, CH4, C2H6, C2H4, O2, and N2 in 1-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide: comparison to other ionic liquids. Accounts of Chemical Research. ,vol. 40, pp. 1208- 1216 ,(2007) , 10.1021/AR7001649
Ibrahim Bou Malham, Mireille Turmine, Viscosities and refractive indices of binary mixtures of 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-2,3-dimethylimidazolium tetrafluoroborate with water at 298K The Journal of Chemical Thermodynamics. ,vol. 40, pp. 718- 723 ,(2008) , 10.1016/J.JCT.2007.10.002
Allan N. Soriano, Bonifacio T. Doma, Meng-Hui Li, Measurements of the density and refractive index for 1-n-butyl-3-methylimidazolium-based ionic liquids The Journal of Chemical Thermodynamics. ,vol. 41, pp. 301- 307 ,(2009) , 10.1016/J.JCT.2008.08.010
A Shariati, C.J Peters, High-pressure phase behavior of systems with ionic liquids: II. The binary system carbon dioxide+1-ethyl-3-methylimidazolium hexafluorophosphate Journal of Supercritical Fluids. ,vol. 29, pp. 43- 48 ,(2004) , 10.1016/S0896-8446(03)00032-9
Andreas P. Fröba, Heiko Kremer, Alfred Leipertz, Density, Refractive Index, Interfacial Tension, and Viscosity of Ionic Liquids [EMIM][EtSO4], [EMIM][NTf2], [EMIM][N(CN)2], and [OMA][NTf2] in Dependence on Temperature at Atmospheric Pressure Journal of Physical Chemistry B. ,vol. 112, pp. 12420- 12430 ,(2008) , 10.1021/JP804319A
Urszula Domańska, Thermophysical properties and thermodynamic phase behavior of ionic liquids Thermochimica Acta. ,vol. 448, pp. 19- 30 ,(2006) , 10.1016/J.TCA.2006.06.018
Jacek Kumełan, Álvaro Pérez-Salado Kamps, Dirk Tuma, Akimichi Yokozeki, Mark B. Shiflett, Gerd Maurer, Solubility of tetrafluoromethane in the ionic liquid [hmim][Tf2N]. Journal of Physical Chemistry B. ,vol. 112, pp. 3040- 3047 ,(2008) , 10.1021/JP076737T
Maggel Deetlefs, Kenneth R. Seddon, Michael Shara, Predicting physical properties of ionic liquids Physical Chemistry Chemical Physics. ,vol. 8, pp. 642- 649 ,(2006) , 10.1039/B513453F